Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 17190-29-3, is researched, SMILESS is N#CCC(O)C1=CC=CC=C1, Molecular C9H9NOJournal, Tetrahedron Letters called One step conversion of highly dipolarophilic olefins to α-hydroxy-β-cyanoadducts with metal fulminate, Author is You, Zhengqing; Lee, Henry Joung, the main research direction is dipolarophile olefin cyanohydroxylation metal fulminate; mercuric fulminate olefin cyanohydroxylation.Related Products of 17190-29-3.
Olefins conjugated with carbonyl, carboxylic ester, and Ph groups as well as highly strained non-conjugated olefin norbornylene were converted to their corresponding α-hydroxy-β-cyanoadducts by treatment with mercuric fulminate and lithium bromide. The transformation appears to go through a 1,3-dipolar cycloaddition of metal fulminate to the olefin followed by a spontaneous cleavage of the resulting heterocycle. Thus, the study provides the first one step cis-cyanohydroxylation of olefinic species.
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Reference:
Pyrazole – Wikipedia,
Pyrazoles – an overview | ScienceDirect Topics