Application of 1300746-79-5. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: (1,10-Phenanthroline)(trifluoromethyl)copper(I), is researched, Molecular C13H8CuF3N2, CAS is 1300746-79-5, about Interrupting the Barton-McCombie Reaction: Aqueous Deoxygenative Trifluoromethylation of O-Alkyl Thiocarbonates. Author is Liu, Zhi-Yun; Cook, Silas P..
The site-selective trifluoromethylation of aliphatic systems remains an important challenge. A light-driven, copper-mediated trifluoromethylation of O-alkyl thiocarbonates was described for the synthesis of trifluoromethyl-alkanes. The reaction provided broad functional group tolerance (e.g., alkyne, alkene, phenol, free alcs., electron-rich and -deficient arenes), thereby offering orthogonality and practicality for trifluoromethylation. A radical organometallic mechanism was proposed.
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Reference:
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Pyrazoles – an overview | ScienceDirect Topics