Electric Literature of 5932-27-4, Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. 5932-27-4, Name is Ethyl 1H-pyrazole-3-carboxylate, SMILES is O=C(C1=NNC=C1)OCC, belongs to pyrazoles-derivatives compound. In a article, author is Kolodziej, Herbert, introduce new discover of the category.
Studies on Bignoniaceae: Newbouldiosides D – F, Minor Phenylethanoid Glycosides from Newbouldia laevis , and New Flavonoids from Markhamia zanzibarica and Spathodea campanulata (#)
Continued examination of the stem bark of Newbouldia laevis afforded three minor phenylethanoid glycosides, designated as newbouldiosides D-F. Their structures were elucidated by spectroscopic methods as beta -(3,4-dihydroxyphenyl)ethyl 5- O -syringoyl- beta – D -apiofuranosyloxy-(1 -> 2)- O -[ alpha -L-rhamnopyranosyl-(1 -> 3)]-6- O -E-sinapoyl- beta -D-glucopyranoside, beta -(3,4-dihydroxyphenyl)ethyl beta -D-apiofuranosyloxy-(1 -> 2)- O -[ alpha -L-rhamnopyranosyl-(1 -> 3)]-6- O -E-sinapoyl- beta -D-glucopyranoside, and beta -(3,4-dihydroxyphenyl)ethyl beta -D-apiofuranosyloxy-(1 -> 2)- O – alpha -L-rhamnopyranosyl-(1 -> 2)-6- O -E-sinapoyl- beta – D -glucopyranoside, respectively. These metabolites are the first members possessing a sinapoyl structural element. In addition, the series of naturally occurring flavonoids is extended by the identification of 3 ‘ ,4 ‘ ,5,7-tetrahydroxy-5 ‘ -methoxyflavanone and apigenin-5- O – alpha -L-rhamnopyranosyl-7- O – beta -D-glucopyranoside obtained from leaf extracts of Markhamia zanzibarica and aromadendrin-7- O -(2 ”- O -formyl)- beta -D-glucopyranoside isolated from Spathodea campanulata. The latter compound is the first example of a flavonoid possessing a formylated glucosyl moiety.
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Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics