{"id":9555,"date":"2022-04-08T05:13:06","date_gmt":"2022-04-07T21:13:06","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=9555"},"modified":"2022-04-08T05:13:06","modified_gmt":"2022-04-07T21:13:06","slug":"the-effect-of-reaction-temperature-change-on-equilibrium-17190-29-3-2","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=9555","title":{"rendered":"The effect of  reaction temperature change on equilibrium 17190-29-3"},"content":{"rendered":"<p>The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 3-Hydroxy-3-phenylpropanenitrile(SMILESS: N#CCC(O)C1=CC=CC=C1,cas:17190-29-3) is researched.<a href=\"https:\/\/www.ambeed.com\/products\/17190-29-3.html\">Related Products of 814-94-8<\/a>. The article \u300aIonization of an \u03b1-hydrogen of acetonitrile by n-butyllithium and alkali amides. Condensations with ketones and aldehydes to form \u03b2-hydroxynitriles\u300b in relation to this compound, is published in Journal of Organic Chemistry. Let&#8217;s take a look at the latest research on this compound (cas:17190-29-3).<\/p>\n<p>MeCN underwent mainly ionization of an \u03b1-H with BuLi in tetrahydrofuran-hexane, rather than an addition reaction involving the CN group. The former course of reaction was evidenced by an addition of the resulting lithioacetonitrile to benzophenone (I), to form 89% 3-hydroxy-3,3-diphenylpropanonitrile. Similarly, an \u03b1-H of MeCN was ionized by Na, Li, and K amides in liquid NH3 and the resulting alkali acetonitrile condensed with I to give this \u03b2-hydroxynitrile in 93, 85, and 69% yields, resp. The BuLi method was extended to several other ketones and to BzH. These results illustrate convenient methods for the synthesis of such \u03b2-hydroxynitriles, which can be dehydrated with acid to form the corresponding unsaturated nitriles. 26 references.<\/p>\n<p>I hope my short article helps more people learn about this compound(3-Hydroxy-3-phenylpropanenitrile)<a href=\"https:\/\/www.ambeed.com\/products\/17190-29-3.html\">Recommanded Product: 17190-29-3<\/a>. Apart from the compound(17190-29-3), you can read my other articles to know other related compounds.<\/p>\n<p>Reference:<br \/><a href=\"https:\/\/en.wikipedia.org\/wiki\/Pyrazole\">Pyrazole &#8211; Wikipedia<\/a>,<br \/><a href=\"https:\/\/www.sciencedirect.com\/topics\/chemistry\/pyrazoles\">Pyrazoles &#8211; an overview | ScienceDirect Topics<\/A><\/p>\n","protected":false},"excerpt":{"rendered":"<p>I hope my short article helps more people learn about this compound(3-Hydroxy-3-phenylpropanenitrile)<a href=\"https:\/\/www.ambeed.com\/products\/17190-29-3.html\">Recommanded Product: 17190-29-3<\/a>. Apart from the compound(17190-29-3), you can read my other articles to know other related compounds.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[723,131],"tags":[126],"class_list":["post-9555","post","type-post","status-publish","format-standard","hentry","category-17190-29-3","category-pyrazoles-derivatives","tag-m-w100-200"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>The effect of reaction temperature change on equilibrium 17190-29-3 | pyrazoles-derivatives<\/title>\n<meta name=\"description\" content=\"The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 3-Hydroxy-3-phenylpropanenitrile(SMILESS: N#CCC(O)C1=CC=CC=C1,cas:17190-29-3) is researched.Related Products of 814-94-8. The article \u300aIonization of an \u03b1-hydrogen of acetonitrile by n-butyllithium and alkali amides. Condensations with ketones and aldehydes to form \u03b2-hydroxynitriles\u300b in relation to this compound, is published in Journal of Organic Chemistry. Let&#039;s take a look at the latest research on this compound (cas:17190-29-3).\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.pyrazoles-derivatives.com\/?p=9555\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"The effect of reaction temperature change on equilibrium 17190-29-3 | pyrazoles-derivatives\" \/>\n<meta property=\"og:description\" content=\"The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 3-Hydroxy-3-phenylpropanenitrile(SMILESS: N#CCC(O)C1=CC=CC=C1,cas:17190-29-3) is researched.Related Products of 814-94-8. The article \u300aIonization of an \u03b1-hydrogen of acetonitrile by n-butyllithium and alkali amides. Condensations with ketones and aldehydes to form \u03b2-hydroxynitriles\u300b in relation to this compound, is published in Journal of Organic Chemistry. 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Compound: 3-Hydroxy-3-phenylpropanenitrile(SMILESS: N#CCC(O)C1=CC=CC=C1,cas:17190-29-3) is researched.Related Products of 814-94-8. The article \u300aIonization of an \u03b1-hydrogen of acetonitrile by n-butyllithium and alkali amides. Condensations with ketones and aldehydes to form \u03b2-hydroxynitriles\u300b in relation to this compound, is published in Journal of Organic Chemistry. 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Compound: 3-Hydroxy-3-phenylpropanenitrile(SMILESS: N#CCC(O)C1=CC=CC=C1,cas:17190-29-3) is researched.Related Products of 814-94-8. The article \u300aIonization of an \u03b1-hydrogen of acetonitrile by n-butyllithium and alkali amides. Condensations with ketones and aldehydes to form \u03b2-hydroxynitriles\u300b in relation to this compound, is published in Journal of Organic Chemistry. Let's take a look at the latest research on this compound (cas:17190-29-3).","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/www.pyrazoles-derivatives.com\/?p=9555","og_locale":"en_US","og_type":"article","og_title":"The effect of reaction temperature change on equilibrium 17190-29-3 | pyrazoles-derivatives","og_description":"The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 3-Hydroxy-3-phenylpropanenitrile(SMILESS: N#CCC(O)C1=CC=CC=C1,cas:17190-29-3) is researched.Related Products of 814-94-8. The article \u300aIonization of an \u03b1-hydrogen of acetonitrile by n-butyllithium and alkali amides. Condensations with ketones and aldehydes to form \u03b2-hydroxynitriles\u300b in relation to this compound, is published in Journal of Organic Chemistry. 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