{"id":9441,"date":"2022-03-31T12:08:26","date_gmt":"2022-03-31T04:08:26","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=9441"},"modified":"2022-03-31T12:08:26","modified_gmt":"2022-03-31T04:08:26","slug":"share-an-extended-knowledge-of-a-compound-1300746-79-5","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=9441","title":{"rendered":"Share an extended knowledge of a compound : 1300746-79-5"},"content":{"rendered":"<p>So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Zhang, Hao-Ran; Xiao, Chang; Zhang, Song-Lin; Zhang, Xiaoming researched the compound: (1,10-Phenanthroline)(trifluoromethyl)copper(I)( cas:1300746-79-5 ).<a href=\"https:\/\/www.ambeed.com\/products\/1300746-79-5.html\">Application of 1300746-79-5<\/a>.They published the article \u300aRadical C-H Bond Trifluoromethylation of Alkenes by High-Valent Copper(III) Trifluoromethyl Compounds\u300b about this compound( cas:1300746-79-5 )  in Advanced Synthesis &#038; Catalysis. Keywords: diarylalkene copper trifluoromethyl complex trifluoromethylation; alkene trifluoromethyl preparation. We&#8217;ll tell you more about this compound (cas:1300746-79-5).<\/p>\n<p>A general and selective method is developed that allows direct vinylic C-H bond trifluoromethylation of 1,1-diarylalkenes 4-R1C6H5C(Ar1)=CH2 (R = H, Me, F, CN, etc.; Ar1 = Ph, 3,4-dimethylphenyl, thiophen-2-yl, etc.) and 2-methylidenetricyclo[9.4.0.0(3,8)]pentadeca-1(11),3,5,7,12,14-hexaene by a high-valent copper(III) trifluoromethyl complex, R2Cu(CF3)3 (R2 = 1,10-phenanthroline, pyridine) producing biol. active trifluoromethylated alkenes (as well as trifluoromethylated carbocyclic compounds) (E\/Z)-4-R1C6H5C(Ar1)=CHCF3 and 5-(2,2,2-trifluoroethylidene)-10,11-dihydro-5H-dibenzo[a,d][7]annulene. This fundamental reactivity of Cu(III)-CF3 compounds has thus far been unknown. The presence of a tertiary amine is crucial to this reaction, acting as both a weak base and a single electron transfer (SET) promoter to abstract the vinylic hydrogen. This method starts from bulk olefins under cost-effective conditions (without the need for external noble metal photocatalyst or stoichiometric amounts of oxidant), and thus is valuable for practical and sustainable applications.<\/p>\n<p>There is still a lot of research devoted to this compound(SMILES\uff1aF[C-](F)([Cu+]1[N]2=C3C4=[N]1C=CC=C4C=CC3=CC=C2)F)<a href=\"https:\/\/www.ambeed.com\/products\/1300746-79-5.html\">Application of 1300746-79-5<\/a>, and with the development of science, more effects of this compound(1300746-79-5) can be discovered.<\/p>\n<p>Reference:<br \/><a href=\"https:\/\/en.wikipedia.org\/wiki\/Pyrazole\">Pyrazole &#8211; Wikipedia<\/a>,<br \/><a href=\"https:\/\/www.sciencedirect.com\/topics\/chemistry\/pyrazoles\">Pyrazoles &#8211; an overview | ScienceDirect Topics<\/A><\/p>\n","protected":false},"excerpt":{"rendered":"<p>There is still a lot of research devoted to this compound(SMILES\uff1aF[C-](F)([Cu+]1[N]2=C3C4=[N]1C=CC=C4C=CC3=CC=C2)F)<a href=\"https:\/\/www.ambeed.com\/products\/1300746-79-5.html\">Application of 1300746-79-5<\/a>, and with the development of science, more effects of this compound(1300746-79-5) can be discovered.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[726,131],"tags":[167],"class_list":["post-9441","post","type-post","status-publish","format-standard","hentry","category-1300746-79-5","category-pyrazoles-derivatives","tag-m-w300-400"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Share an extended knowledge of a compound : 1300746-79-5 | pyrazoles-derivatives<\/title>\n<meta name=\"description\" content=\"So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Zhang, Hao-Ran; Xiao, Chang; Zhang, Song-Lin; Zhang, Xiaoming researched the compound: (1,10-Phenanthroline)(trifluoromethyl)copper(I)( cas:1300746-79-5 ).Application of 1300746-79-5.They published the article \u300aRadical C-H Bond Trifluoromethylation of Alkenes by High-Valent Copper(III) Trifluoromethyl Compounds\u300b about this compound( cas:1300746-79-5 ) in Advanced Synthesis &amp; Catalysis. Keywords: diarylalkene copper trifluoromethyl complex trifluoromethylation; alkene trifluoromethyl preparation. 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We'll tell you more about this compound (cas:1300746-79-5).","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/www.pyrazoles-derivatives.com\/?p=9441","og_locale":"en_US","og_type":"article","og_title":"Share an extended knowledge of a compound : 1300746-79-5 | pyrazoles-derivatives","og_description":"So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Zhang, Hao-Ran; Xiao, Chang; Zhang, Song-Lin; Zhang, Xiaoming researched the compound: (1,10-Phenanthroline)(trifluoromethyl)copper(I)( cas:1300746-79-5 ).Application of 1300746-79-5.They published the article \u300aRadical C-H Bond Trifluoromethylation of Alkenes by High-Valent Copper(III) Trifluoromethyl Compounds\u300b about this compound( cas:1300746-79-5 ) in Advanced Synthesis & Catalysis. Keywords: diarylalkene copper trifluoromethyl complex trifluoromethylation; alkene trifluoromethyl preparation. We'll tell you more about this compound (cas:1300746-79-5).","og_url":"https:\/\/www.pyrazoles-derivatives.com\/?p=9441","og_site_name":"pyrazoles-derivatives","article_published_time":"2022-03-31T04:08:26+00:00","author":"Jessica.F","twitter_card":"summary_large_image","twitter_misc":{"Written by":"Jessica.F","Est. reading time":"2 minutes"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"WebPage","@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=9441","url":"https:\/\/www.pyrazoles-derivatives.com\/?p=9441","name":"Share an extended knowledge of a compound : 1300746-79-5 | pyrazoles-derivatives","isPartOf":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/#website"},"datePublished":"2022-03-31T04:08:26+00:00","author":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1"},"description":"So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Zhang, Hao-Ran; Xiao, Chang; Zhang, Song-Lin; Zhang, Xiaoming researched the compound: (1,10-Phenanthroline)(trifluoromethyl)copper(I)( cas:1300746-79-5 ).Application of 1300746-79-5.They published the article \u300aRadical C-H Bond Trifluoromethylation of Alkenes by High-Valent Copper(III) Trifluoromethyl Compounds\u300b about this compound( cas:1300746-79-5 ) in Advanced Synthesis & Catalysis. Keywords: diarylalkene copper trifluoromethyl complex trifluoromethylation; alkene trifluoromethyl preparation. 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