{"id":7924,"date":"2021-11-30T05:18:04","date_gmt":"2021-11-29T21:18:04","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=7924"},"modified":"2021-11-30T05:18:04","modified_gmt":"2021-11-29T21:18:04","slug":"final-thoughts-on-chemistry-for-1159408-72-6","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=7924","title":{"rendered":"Final Thoughts on Chemistry for 1159408-72-6"},"content":{"rendered":"<p>Today I&#8217;d like to introduce a new chemical compound, CAS is 1159408-72-6, <a href=\"https:\/\/www.ambeed.com\/products\/1159408-72-6.html\">SDS of cas: 1159408-72-6<\/a>, Name is (2S,4R)-2-[[Bis(4-methoxyphenyl)phenylmethoxy]methyl]-4-hydroxy-\u03bb-oxo-N-[2-[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]-1,1-bis[[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]methyl]ethyl]-1-pyrrolidinedodecanamide, Formula is C117H175N11O42, Molecular Weight is 2407.69g\/mol. Because of its complex structure and huge molecular weight, this compound is rarely understood. Now let me introduce some knowledge about its synthesis.<\/p>\n<p>The general reactant of this compound is (3R,5S)-5-[[Bis(4-methoxyphenyl)phenylmethoxy]methyl]-3-pyrrolidinol, 12,19,25-Trioxo-14,14-bis[[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]methyl]-29-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]-16-oxa-13,20,24-triazanonacosanoic acid, Reagents is Diisopropylethylamine, 1-[Bis(dimethylamino)methylene]-1H-benzotriazolium hexafluorophosphate(1-) 3-oxide, Catalyst(), Solvent is Dichloromethane, Products (2S,4R)-2-[[Bis(4-methoxyphenyl)phenylmethoxy]methyl]-4-hydroxy-\u03bb-oxo-N-[2-[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]-1,1-bis[[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]methyl]ethyl]-1-pyrrolidinedodecanamide, Yield:\u00a073%, Synthetic Methods procedure :1. Add HBTU ( 2.10 g, 5.55 mmol ) and DIEA ( 3 mL, 17 mmol ) to a solution of the acid ( 10.13 g, 5.05 mmol ) and amine ( 2.32 g, 5.55 mmol ) in DCM ( 100 mL ) ., 2. Stir the mixture for 2 hours at room temperature., 3. Dilute the reaction mixture with DCM and wash with water., 4. Purify the crude product by silica gel chromatography ( eluent: 3-15 % MeOH in DCM containing 0.1% Et3N ) ., Acylation of Nitrogen Nucleophiles by Carboxylic Acids, Transfornation (Acylation of Nitrogen Nucleophiles by Carboxylic Acids. Characterization Data include &#8216;s Proton NMR Spectrum : ( 400 MHz, DMSO-d\u00a06, mixture of rotamers: ~0.7 ( major ) , ~0.3 ( minor ) ) : \u03b47.87-7.79 ( m, 6H,\u00a0NH\u00a0) , 7.73 ( t,\u00a0J\u00a0= 5.6 Hz, 3H,\u00a0NH\u00a0) ; 7.34-7.24 ( m, 4H ) ; 7.24-7.14 ( m, 5H ) ; 6.97 ( s, 1H,\u00a0NH\u00a0) ; 6.90-6.82 ( m, 4H ) ; 5.20 ( d,\u00a0J\u00a0= 3.4, 3H,\u00a0sugar\u00a0H4\u00a0) ; 4.99-4.93 ( m, 3.7H ) ; 4.88 ( d,\u00a0J\u00a0= 4.2, 0.3H, OH ) ; 4.48 ( d,\u00a0J\u00a0= 8.4, 3H,\u00a0sugar H1\u00a0) ; 4.42-4.34 ( m, 0.7H ) ; 4.32-4.24 ( m, 0.3H ) ; 4.17-4.07 ( m, 1H ) ; 4.05-3.97 ( m, 9H,\u00a0sugar\u00a0H5, H6, H6\u2032\u00a0) ; 3.86 ( dt,\u00a0J\u00a0= 8.8, 10.9 Hz, 3H,\u00a0sugar H2\u00a0) ; 3.72 ( s, 6H ) ; 3.69 ( dt,\u00a0J\u00a0= 5.4, 9.8 Hz, 3H ) ; 3.62-3.44 ( m, 13H ) ; 3.39 ( dt,\u00a0J\u00a0= 6.4, 9.9 Hz, 3H ) ; 3.35-3.28 ( m, 0.7H ) ; 3.27-3.21 ( m, 0.3H ) ; 3.18-3.12 ( m, 1H ) ; 3.11-2.93 ( m, 13H ) ; 2.27 ( t,\u00a0J\u00a0= 6.2, 6H ) ; 2.19 ( t,\u00a0J\u00a0= 7.5, 1.7H ) ; 2.09 ( s, 9H ) ; 2.03 ( t,\u00a0J\u00a0= 7.3, 8.3H ) ; 1.98 ( s, 9H ) ; 1.96-1.80 ( m, 2H ) ; 1.89 ( s, 9H ) ; 1.76 ( s, 9H ) ; 1.55-1.37 ( m, 22H ) ; 1.12-1.30 ( m, 12H ) ., Carbon-13 NMR : ( 101 MHz, DMSO-d\u00a06\u00a0) : \u03b4 172.5, 172.0, 171.6, 171.2, 171.1, 171.0, 170.1, 170.00; 169.9; 169.6, 169.4, 158.1, 158.0, 157.8, 148.4, 145.1, 144.8, 140.2, 135.9, 135.8, 135.5, 135.4, 129.6, 128.9, 127.9, 127.8, 127.7, 127.6, 127.4, 126.6, 126.4, 113.2, 113.1, 112.7, 101.0, 85.8, 85.1, 79.9, 70.5, 69.8, 68.7, 68.3, 67.3, 66.7, 63.4, 62.1, 61.4, 59.5, 57.6, 55.2, 55.1, 55.0, 55.0, 54.9, 49.4, 36.4, 36.3, 36.0, 35.9, 35.1, 34.3, 29.3, 29.0, 28.6, 28.6, 25.3, 24.5, 24.5, 22.8, 21.9, 20.5, 20.4., Mass Spectrum: Mass calc. for C117H175N11O42\u00a02406.19; found 2429.18 ( M+Na+, MALDI-TOF, matrix: HABA ) ., State is white solid<\/p>\n<p>I&#8217;m so glad you had the patience to read the whole article, if you want know more about 1159408-72-6, <a href=\"https:\/\/www.ambeed.com\/products\/1159408-72-6.html\">SDS of cas: 1159408-72-6<\/a>, you can browse my other blog.<\/p>\n<p>Reference:<br \/><a href=https:\/\/pubs.acs.org\/doi\/10.1021\/ja505986a>CAS Method Number\u00a03-355-CAS-9994399<\/a>,<br \/>,<a href=https:\/\/pubs.acs.org\/doi\/10.1021\/ja505986a>CAS Method Number\u00a03-010-CAS-8275923<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>I&#8217;m so glad you had the patience to read the whole article, if you want know more about 1159408-72-6, <a href=\"https:\/\/www.ambeed.com\/products\/1159408-72-6.html\">SDS of cas: 1159408-72-6<\/a>, you can browse my other blog.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[721,131],"tags":[722],"class_list":["post-7924","post","type-post","status-publish","format-standard","hentry","category-1159408-72-6","category-pyrazoles-derivatives","tag-m-w2000-2500"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Final Thoughts on Chemistry for 1159408-72-6 | pyrazoles-derivatives<\/title>\n<meta name=\"description\" content=\"Today I&#039;d like to introduce a new chemical compound, CAS is 1159408-72-6, SDS of cas: 1159408-72-6, Name is (2S,4R)-2-[[Bis(4-methoxyphenyl)phenylmethoxy]methyl]-4-hydroxy-\u03bb-oxo-N-[2-[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]-1,1-bis[[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]methyl]ethyl]-1-pyrrolidinedodecanamide, Formula is C117H175N11O42, Molecular Weight is 2407.69g\/mol. Because of its complex structure and huge molecular weight, this compound is rarely understood. 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Because of its complex structure and huge molecular weight, this compound is rarely understood. 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Because of its complex structure and huge molecular weight, this compound is rarely understood. Now let me introduce some knowledge about its synthesis.\",\"breadcrumb\":{\"@id\":\"http:\/\/www.pyrazoles-derivatives.com\/?p=7924#breadcrumb\"},\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"http:\/\/www.pyrazoles-derivatives.com\/?p=7924\"]}]},{\"@type\":\"BreadcrumbList\",\"@id\":\"http:\/\/www.pyrazoles-derivatives.com\/?p=7924#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"\u9996\u9875\",\"item\":\"http:\/\/www.pyrazoles-derivatives.com\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"Final Thoughts on Chemistry for 1159408-72-6\"}]},{\"@type\":\"WebSite\",\"@id\":\"http:\/\/www.pyrazoles-derivatives.com\/#website\",\"url\":\"http:\/\/www.pyrazoles-derivatives.com\/\",\"name\":\"pyrazoles-derivatives\",\"description\":\"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. 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Because of its complex structure and huge molecular weight, this compound is rarely understood. Now let me introduce some knowledge about its synthesis.","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"http:\/\/www.pyrazoles-derivatives.com\/?p=7924","og_locale":"en_US","og_type":"article","og_title":"Final Thoughts on Chemistry for 1159408-72-6 | pyrazoles-derivatives","og_description":"Today I'd like to introduce a new chemical compound, CAS is 1159408-72-6, SDS of cas: 1159408-72-6, Name is (2S,4R)-2-[[Bis(4-methoxyphenyl)phenylmethoxy]methyl]-4-hydroxy-\u03bb-oxo-N-[2-[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]-1,1-bis[[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]methyl]ethyl]-1-pyrrolidinedodecanamide, Formula is C117H175N11O42, Molecular Weight is 2407.69g\/mol. Because of its complex structure and huge molecular weight, this compound is rarely understood. Now let me introduce some knowledge about its synthesis.","og_url":"http:\/\/www.pyrazoles-derivatives.com\/?p=7924","og_site_name":"pyrazoles-derivatives","article_published_time":"2021-11-29T21:18:04+00:00","author":"Jessica.F","twitter_card":"summary_large_image","twitter_misc":{"Written by":"Jessica.F","Est. reading time":"2 minutes"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"WebPage","@id":"http:\/\/www.pyrazoles-derivatives.com\/?p=7924","url":"http:\/\/www.pyrazoles-derivatives.com\/?p=7924","name":"Final Thoughts on Chemistry for 1159408-72-6 | pyrazoles-derivatives","isPartOf":{"@id":"http:\/\/www.pyrazoles-derivatives.com\/#website"},"datePublished":"2021-11-29T21:18:04+00:00","author":{"@id":"http:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1"},"description":"Today I'd like to introduce a new chemical compound, CAS is 1159408-72-6, SDS of cas: 1159408-72-6, Name is (2S,4R)-2-[[Bis(4-methoxyphenyl)phenylmethoxy]methyl]-4-hydroxy-\u03bb-oxo-N-[2-[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]-1,1-bis[[3-oxo-3-[[3-[[1-oxo-5-[[3,4,6-tri-O-acetyl-2-(acetylamino)-2-deoxy-\u03b2-D-galactopyranosyl]oxy]pentyl]amino]propyl]amino]propoxy]methyl]ethyl]-1-pyrrolidinedodecanamide, Formula is C117H175N11O42, Molecular Weight is 2407.69g\/mol. Because of its complex structure and huge molecular weight, this compound is rarely understood. Now let me introduce some knowledge about its synthesis.","breadcrumb":{"@id":"http:\/\/www.pyrazoles-derivatives.com\/?p=7924#breadcrumb"},"inLanguage":"en-US","potentialAction":[{"@type":"ReadAction","target":["http:\/\/www.pyrazoles-derivatives.com\/?p=7924"]}]},{"@type":"BreadcrumbList","@id":"http:\/\/www.pyrazoles-derivatives.com\/?p=7924#breadcrumb","itemListElement":[{"@type":"ListItem","position":1,"name":"\u9996\u9875","item":"http:\/\/www.pyrazoles-derivatives.com\/"},{"@type":"ListItem","position":2,"name":"Final Thoughts on Chemistry for 1159408-72-6"}]},{"@type":"WebSite","@id":"http:\/\/www.pyrazoles-derivatives.com\/#website","url":"http:\/\/www.pyrazoles-derivatives.com\/","name":"pyrazoles-derivatives","description":"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. 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