{"id":6888,"date":"2021-10-15T03:33:59","date_gmt":"2021-10-14T19:33:59","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=6888"},"modified":"2021-10-15T03:33:59","modified_gmt":"2021-10-14T19:33:59","slug":"awesome-and-easy-science-experiments-about-35-dimethyl-1h-pyrazole","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=6888","title":{"rendered":"Awesome and Easy Science Experiments about 3,5-Dimethyl-1H-pyrazole"},"content":{"rendered":"

Torres, JF; Macias, MA; Franco-Ulloa, S; Miscione, GP; Cobo, J; Hurtado, JJ in [Torres, Juan F.; Macias, Mario A.; Hurtado, John J.] Univ Los Andes, Dept Chem, Carrera 1 18A-12, Bogota 111711, Colombia; [Franco-Ulloa, Sebastian; Pietro Miscione, Gian] Univ Los Andes, Chem Dept, COBO Computat Bioorgan Chem Bogota, Cra 1 18A-12, Bogota 111711, Colombia; [Cobo, Justo] Univ Jaen, Dept Inorgan & Organ Chem, Jaen 23071, Spain published Cu(II) and Zn(II) Complexes with Dinitrobenzoates and Pyrazolyl Ligands: Structural and Thermal Stability Influence of N-H Moiety in 2019, Cited 53. COA of Formula: C5H8N2<\/a>. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.<\/p>\n

The synthesis and characterization of air-stable Cu(II) and Zn(II) complexes with 3,5-dinitrobenzoate (DNB) and 3,5-dimethylpyrazole (L1) or bis(3,5-dimethylpyrazol-1-yl)methane (L2) are described. Three of these complexes exhibit a monomeric structure, while the Cu(II) complex with L2 is a trinuclear complex. Density functional theory calculations were performed to understand the unexpected formation of the three-centered compound. In agreement with the X-ray crystal structure, the N-H moiety present in LI was identified as possible driving force to obtain monomeric structures, while L2, without it, can favor the trinuclear complex formation. Thermal studies were carried for the complexes, and it was observed that the presence of the azole ligand allows the decomposition of the complexes at lower temperatures due to the presence of acidic protons, being especially important for L1.<\/p>\n

COA of Formula: C5H8N2<\/a>. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Torres, JF; Macias, MA; Franco-Ulloa, S; Miscione, GP; Cobo, J; Hurtado, JJ or concate me.<\/p>\n

Reference:
Pyrazole – Wikipedia<\/a>,
,Pyrazoles – an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

COA of Formula: C5H8N2<\/a>. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Torres, JF; Macias, MA; Franco-Ulloa, S; Miscione, GP; Cobo, J; Hurtado, JJ or concate me.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[249,131],"tags":[145],"class_list":["post-6888","post","type-post","status-publish","format-standard","hentry","category-67-51-6","category-pyrazoles-derivatives","tag-m-w0-100"],"yoast_head":"\nAwesome and Easy Science Experiments about 3,5-Dimethyl-1H-pyrazole | pyrazoles-derivatives<\/title>\n<meta name=\"description\" content=\"Torres, JF; Macias, MA; Franco-Ulloa, S; Miscione, GP; Cobo, J; Hurtado, JJ in [Torres, Juan F.; Macias, Mario A.; Hurtado, John J.] Univ Los Andes, Dept Chem, Carrera 1 18A-12, Bogota 111711, Colombia; [Franco-Ulloa, Sebastian; Pietro Miscione, Gian] Univ Los Andes, Chem Dept, COBO Computat Bioorgan Chem Bogota, Cra 1 18A-12, Bogota 111711, Colombia; [Cobo, Justo] Univ Jaen, Dept Inorgan & Organ Chem, Jaen 23071, Spain published Cu(II) and Zn(II) Complexes with Dinitrobenzoates and Pyrazolyl Ligands: Structural and Thermal Stability Influence of N-H Moiety in 2019, Cited 53. COA of Formula: C5H8N2. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.pyrazoles-derivatives.com\/?p=6888\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Awesome and Easy Science Experiments about 3,5-Dimethyl-1H-pyrazole | pyrazoles-derivatives\" \/>\n<meta property=\"og:description\" content=\"Torres, JF; Macias, MA; Franco-Ulloa, S; Miscione, GP; Cobo, J; Hurtado, JJ in [Torres, Juan F.; Macias, Mario A.; Hurtado, John J.] Univ Los Andes, Dept Chem, Carrera 1 18A-12, Bogota 111711, Colombia; [Franco-Ulloa, Sebastian; Pietro Miscione, Gian] Univ Los Andes, Chem Dept, COBO Computat Bioorgan Chem Bogota, Cra 1 18A-12, Bogota 111711, Colombia; [Cobo, Justo] Univ Jaen, Dept Inorgan & Organ Chem, Jaen 23071, Spain published Cu(II) and Zn(II) Complexes with Dinitrobenzoates and Pyrazolyl Ligands: Structural and Thermal Stability Influence of N-H Moiety in 2019, Cited 53. COA of Formula: C5H8N2. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.pyrazoles-derivatives.com\/?p=6888\" \/>\n<meta property=\"og:site_name\" content=\"pyrazoles-derivatives\" \/>\n<meta property=\"article:published_time\" content=\"2021-10-14T19:33:59+00:00\" \/>\n<meta name=\"author\" content=\"Jessica.F\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Jessica.F\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minute\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=6888\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=6888\",\"name\":\"Awesome and Easy Science Experiments about 3,5-Dimethyl-1H-pyrazole | pyrazoles-derivatives\",\"isPartOf\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\"},\"datePublished\":\"2021-10-14T19:33:59+00:00\",\"author\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1\"},\"description\":\"Torres, JF; Macias, MA; Franco-Ulloa, S; Miscione, GP; Cobo, J; Hurtado, JJ in [Torres, Juan F.; Macias, Mario A.; Hurtado, John J.] Univ Los Andes, Dept Chem, Carrera 1 18A-12, Bogota 111711, Colombia; [Franco-Ulloa, Sebastian; Pietro Miscione, Gian] Univ Los Andes, Chem Dept, COBO Computat Bioorgan Chem Bogota, Cra 1 18A-12, Bogota 111711, Colombia; [Cobo, Justo] Univ Jaen, Dept Inorgan & Organ Chem, Jaen 23071, Spain published Cu(II) and Zn(II) Complexes with Dinitrobenzoates and Pyrazolyl Ligands: Structural and Thermal Stability Influence of N-H Moiety in 2019, Cited 53. COA of Formula: C5H8N2. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.\",\"breadcrumb\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=6888#breadcrumb\"},\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\/\/www.pyrazoles-derivatives.com\/?p=6888\"]}]},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=6888#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"\u9996\u9875\",\"item\":\"https:\/\/www.pyrazoles-derivatives.com\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"Awesome and Easy Science Experiments about 3,5-Dimethyl-1H-pyrazole\"}]},{\"@type\":\"WebSite\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/\",\"name\":\"pyrazoles-derivatives\",\"description\":\"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. Pyrazole derivatives play an important role in antitumor agents.\",\"potentialAction\":[{\"@type\":\"SearchAction\",\"target\":{\"@type\":\"EntryPoint\",\"urlTemplate\":\"https:\/\/www.pyrazoles-derivatives.com\/?s={search_term_string}\"},\"query-input\":{\"@type\":\"PropertyValueSpecification\",\"valueRequired\":true,\"valueName\":\"search_term_string\"}}],\"inLanguage\":\"en-US\"},{\"@type\":\"Person\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1\",\"name\":\"Jessica.F\",\"image\":{\"@type\":\"ImageObject\",\"inLanguage\":\"en-US\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/image\/\",\"url\":\"https:\/\/weavatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g\",\"contentUrl\":\"https:\/\/weavatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g\",\"caption\":\"Jessica.F\"}}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Awesome and Easy Science Experiments about 3,5-Dimethyl-1H-pyrazole | pyrazoles-derivatives","description":"Torres, JF; Macias, MA; Franco-Ulloa, S; Miscione, GP; Cobo, J; Hurtado, JJ in [Torres, Juan F.; Macias, Mario A.; Hurtado, John J.] Univ Los Andes, Dept Chem, Carrera 1 18A-12, Bogota 111711, Colombia; [Franco-Ulloa, Sebastian; Pietro Miscione, Gian] Univ Los Andes, Chem Dept, COBO Computat Bioorgan Chem Bogota, Cra 1 18A-12, Bogota 111711, Colombia; [Cobo, Justo] Univ Jaen, Dept Inorgan & Organ Chem, Jaen 23071, Spain published Cu(II) and Zn(II) Complexes with Dinitrobenzoates and Pyrazolyl Ligands: Structural and Thermal Stability Influence of N-H Moiety in 2019, Cited 53. COA of Formula: C5H8N2. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/www.pyrazoles-derivatives.com\/?p=6888","og_locale":"en_US","og_type":"article","og_title":"Awesome and Easy Science Experiments about 3,5-Dimethyl-1H-pyrazole | pyrazoles-derivatives","og_description":"Torres, JF; Macias, MA; Franco-Ulloa, S; Miscione, GP; Cobo, J; Hurtado, JJ in [Torres, Juan F.; Macias, Mario A.; Hurtado, John J.] Univ Los Andes, Dept Chem, Carrera 1 18A-12, Bogota 111711, Colombia; [Franco-Ulloa, Sebastian; Pietro Miscione, Gian] Univ Los Andes, Chem Dept, COBO Computat Bioorgan Chem Bogota, Cra 1 18A-12, Bogota 111711, Colombia; [Cobo, Justo] Univ Jaen, Dept Inorgan & Organ Chem, Jaen 23071, Spain published Cu(II) and Zn(II) Complexes with Dinitrobenzoates and Pyrazolyl Ligands: Structural and Thermal Stability Influence of N-H Moiety in 2019, Cited 53. COA of Formula: C5H8N2. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.","og_url":"https:\/\/www.pyrazoles-derivatives.com\/?p=6888","og_site_name":"pyrazoles-derivatives","article_published_time":"2021-10-14T19:33:59+00:00","author":"Jessica.F","twitter_card":"summary_large_image","twitter_misc":{"Written by":"Jessica.F","Est. reading time":"1 minute"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"WebPage","@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=6888","url":"https:\/\/www.pyrazoles-derivatives.com\/?p=6888","name":"Awesome and Easy Science Experiments about 3,5-Dimethyl-1H-pyrazole | pyrazoles-derivatives","isPartOf":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/#website"},"datePublished":"2021-10-14T19:33:59+00:00","author":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1"},"description":"Torres, JF; Macias, MA; Franco-Ulloa, S; Miscione, GP; Cobo, J; Hurtado, JJ in [Torres, Juan F.; Macias, Mario A.; Hurtado, John J.] Univ Los Andes, Dept Chem, Carrera 1 18A-12, Bogota 111711, Colombia; [Franco-Ulloa, Sebastian; Pietro Miscione, Gian] Univ Los Andes, Chem Dept, COBO Computat Bioorgan Chem Bogota, Cra 1 18A-12, Bogota 111711, Colombia; [Cobo, Justo] Univ Jaen, Dept Inorgan & Organ Chem, Jaen 23071, Spain published Cu(II) and Zn(II) Complexes with Dinitrobenzoates and Pyrazolyl Ligands: Structural and Thermal Stability Influence of N-H Moiety in 2019, Cited 53. COA of Formula: C5H8N2. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.","breadcrumb":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=6888#breadcrumb"},"inLanguage":"en-US","potentialAction":[{"@type":"ReadAction","target":["https:\/\/www.pyrazoles-derivatives.com\/?p=6888"]}]},{"@type":"BreadcrumbList","@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=6888#breadcrumb","itemListElement":[{"@type":"ListItem","position":1,"name":"\u9996\u9875","item":"https:\/\/www.pyrazoles-derivatives.com\/"},{"@type":"ListItem","position":2,"name":"Awesome and Easy Science Experiments about 3,5-Dimethyl-1H-pyrazole"}]},{"@type":"WebSite","@id":"https:\/\/www.pyrazoles-derivatives.com\/#website","url":"https:\/\/www.pyrazoles-derivatives.com\/","name":"pyrazoles-derivatives","description":"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. Pyrazole derivatives play an important role in antitumor agents.","potentialAction":[{"@type":"SearchAction","target":{"@type":"EntryPoint","urlTemplate":"https:\/\/www.pyrazoles-derivatives.com\/?s={search_term_string}"},"query-input":{"@type":"PropertyValueSpecification","valueRequired":true,"valueName":"search_term_string"}}],"inLanguage":"en-US"},{"@type":"Person","@id":"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1","name":"Jessica.F","image":{"@type":"ImageObject","inLanguage":"en-US","@id":"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/image\/","url":"https:\/\/weavatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g","contentUrl":"https:\/\/weavatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g","caption":"Jessica.F"}}]}},"_links":{"self":[{"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/posts\/6888","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/users\/8"}],"replies":[{"embeddable":true,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=6888"}],"version-history":[{"count":0,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/posts\/6888\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=6888"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=6888"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=6888"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}