{"id":11754,"date":"2022-12-02T03:54:23","date_gmt":"2022-12-01T19:54:23","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=11754"},"modified":"2022-12-02T03:54:23","modified_gmt":"2022-12-01T19:54:23","slug":"mo-zong-wens-team-published-research-in-crystal-growth-design-in-18-cas-19959-71-8","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=11754","title":{"rendered":"Mo, Zong-Wen&#8217;s team published research in Crystal Growth &amp; Design  in 18 | CAS: 19959-71-8"},"content":{"rendered":"<p>Mo, Zong-Wen published the artcile<b><i>Tuning Connectivity and Flexibility of Two Zinc-Triazolate-Carboxylate Type Porous Coordination Polymers<\/i><\/b>,  <a href=\"https:\/\/www.ambeed.com\/products\/19959-71-8.html\">Recommanded Product: 4-(1H-Pyrazol-4-yl)pyridine<\/a>,  the publication is  Crystal Growth &amp; Design (2018), 18(5), 2694-2698, database is CAplus.<\/p>\n<p>Solvothermal reactions of Zn(II) salts and 4-(1H-pyrazol-4-yl)pyridine (Hpypz) in the presence of monocarboxylate or dicarboxylate ligands produced two porous coordination polymers, namely, [Zn(pypz)(OAc)]\u00b7guest (<strong>1<\/strong>\u00b7g, HOAc = acetic acid) and [Zn<sub>2<\/sub>(pypz)<sub>2<\/sub>(oba)]\u00b7guest (<strong>2<\/strong>\u00b7g, H<sub>2<\/sub>oba = 4,4&#8242;-oxobisbenzoic acid). Single-crystal x-ray diffraction analyses showed that both <strong>1<\/strong> and <strong>2<\/strong> contain 2-fold interpenetrated three-dimensional nbo-a {Zn(pypz)}<sup>+<\/sup> networks consisting of 3-connected Zn(II) ions and 3-connected pypz<sup>&#8211;<\/sup> ligands. After the carboxylate ligands were considered, <strong>1<\/strong> retains the nbo-a network structure and contains one-dimensional channels with very narrow apertures. However, <strong>2<\/strong> becomes a new uninodal 6-connected topol. (point symbol 3<sup>3<\/sup>.4<sup>2<\/sup>.5<sup>6<\/sup>.6<sup>4<\/sup>) and contains discrete pores. Powder x-ray diffraction showed that, after solvent removal, <strong>1<\/strong> undergoes obvious framework shrinkage, while <strong>2<\/strong> retains the original unit cell. Activated <strong>1<\/strong> and <strong>2<\/strong> both exclude N<sub>2<\/sub> at 77 K, but readily adsorb CO<sub>2<\/sub> at 195 K with unconventional isotherm shapes, indicating the different types of framework flexibilities.<\/p>\n<p>Crystal Growth &amp; Design published new progress about 19959-71-8. 19959-71-8 belongs to pyrazoles-derivatives, auxiliary class Pyrazole,Pyridine, name is 4-(1H-Pyrazol-4-yl)pyridine, and the molecular formula is C8H7N3, <a href=\"https:\/\/www.ambeed.com\/products\/19959-71-8.html\">Recommanded Product: 4-(1H-Pyrazol-4-yl)pyridine<\/a>.<\/p>\n<p>Referemce:<br \/><a href=\"https:\/\/en.wikipedia.org\/wiki\/Pyrazole\">https:\/\/en.wikipedia.org\/wiki\/Pyrazole<\/a>,<br \/><a href=\"Pyrazole - Wikipedia\">Pyrazoles &#8211; an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Crystal Growth &amp; Design published new progress about 19959-71-8. 19959-71-8 belongs to pyrazoles-derivatives, auxiliary class Pyrazole,Pyridine, name is 4-(1H-Pyrazol-4-yl)pyridine, and the molecular formula is C8H7N3, <a href=\"https:\/\/www.ambeed.com\/products\/19959-71-8.html\">Recommanded Product: 4-(1H-Pyrazol-4-yl)pyridine<\/a>.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[803,131],"tags":[732],"class_list":["post-11754","post","type-post","status-publish","format-standard","hentry","category-19959-71-8","category-pyrazoles-derivatives","tag-m-w100-150"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Mo, Zong-Wen&#039;s team published research in Crystal Growth &amp; 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