{"id":11744,"date":"2022-12-02T03:54:23","date_gmt":"2022-12-01T19:54:23","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=11744"},"modified":"2022-12-02T03:54:23","modified_gmt":"2022-12-01T19:54:23","slug":"ma-yuans-team-published-research-in-industrial-engineering-chemistry-research-in-57-cas-930-36-9","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=11744","title":{"rendered":"Ma, Yuan&#8217;s team published research in Industrial &amp; Engineering Chemistry Research  in 57 | CAS: 930-36-9"},"content":{"rendered":"<p>Ma, Yuan published the artcile<b><i>Insight on asym-Pyrazolium Ionic Liquids for Chemical Fixation of CO<sub>2<\/sub> and Propylene Epoxide into Propylene Carbonate without Organic Solvent and Metal<\/i><\/b>,  <a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Related Products of pyrazoles-derivatives<\/a>,  the publication is  Industrial &amp; Engineering Chemistry Research (2018), 57(40), 13342-13352, database is CAplus.<\/p>\n<p>From the perspective of environmental protection and resource utilization, the fixation of carbon dioxide (CO<sub>2<\/sub>) is an interesting and meaningful topic. In this work, a series of asym-dialkylpyrazolium ionic liquids are synthesized by us to explore their catalytic activity for the cycloaddition of CO<sub>2<\/sub> and propylene epoxide to produce propylene carbonate (PC). They could be easily synthesized by a simple reaction, which is the premise for the large-scale application. The effect of alkyl chain length in cation on catalytic performance is investigated. Although asym-pyrazolium ILs present less catalytic activity than sym-pyrazolium ILs, the product yield catalyzed by EPPzBr is as high as 85% with PC selectivity of 99%, which is better than most of nonfunctionalized ionic liquids Moreover, the catalyst could be reused at least five times without significant loss of catalytic activity. To elucidate the structure-property relationship, the difference between asym-pyrazolium ILs and sym-pyrazolium ILs is discussed in detail by the Double-IL model associated with the noncovalent interactions and atoms in mol. anal. The kind of single-component catalysts for the fixation of CO<sub>2<\/sub> is further enriched.<\/p>\n<p>Industrial &amp; Engineering Chemistry Research published new progress about 930-36-9. 930-36-9 belongs to pyrazoles-derivatives, auxiliary class Pyrazole, name is 1-Methylpyrazole, and the molecular formula is C4H6N2, <a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Related Products of pyrazoles-derivatives<\/a>.<\/p>\n<p>Referemce:<br \/><a href=\"https:\/\/en.wikipedia.org\/wiki\/Pyrazole\">https:\/\/en.wikipedia.org\/wiki\/Pyrazole<\/a>,<br \/><a href=\"Pyrazole - Wikipedia\">Pyrazoles &#8211; an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Industrial &amp; Engineering Chemistry Research published new progress about 930-36-9. 930-36-9 belongs to pyrazoles-derivatives, auxiliary class Pyrazole, name is 1-Methylpyrazole, and the molecular formula is C4H6N2, <a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Related Products of pyrazoles-derivatives<\/a>.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[245,131],"tags":[784],"class_list":["post-11744","post","type-post","status-publish","format-standard","hentry","category-930-36-9","category-pyrazoles-derivatives","tag-m-w50-100"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Ma, Yuan&#039;s team published research in Industrial &amp; 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