{"id":11703,"date":"2022-12-02T03:51:02","date_gmt":"2022-12-01T19:51:02","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=11703"},"modified":"2022-12-02T03:51:02","modified_gmt":"2022-12-01T19:51:02","slug":"cai-dongrens-team-published-research-in-energy-conversion-and-management-in-166-cas-930-36-9","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=11703","title":{"rendered":"Cai, Dongren&#8217;s team published research in Energy Conversion and Management  in 166 | CAS: 930-36-9"},"content":{"rendered":"<p>Cai, Dongren published the artcile<b><i>Design and synthesis of novel Bronsted-Lewis acidic ionic liquid and its application in biodiesel production from soapberry oil<\/i><\/b>,  <a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Related Products of pyrazoles-derivatives<\/a>,  the publication is  Energy Conversion and Management (2018), 318-327, database is CAplus.<\/p>\n<p>With the combination of mol. simulation and relevant experiments, the efficient Bronsted-Lewis acidic ionic liquid (IL) was designed and synthesized for biodiesel production from soapberry oil. In mol. simulation, 4-methylthiazole (MT) is proved to be the best matrix for IL preparation via electrostatic potential anal. and proton affinity anal., and it also is verified by experiments In orthogonal experiment, the relationship in catalytic activity between Bronsted-Lewis acidic IL and corresponding materials (Bronsted acidic IL and metal chloride) was revealed. Meanwhile, [Ps-MTH][CF<sub>3<\/sub>SO<sub>3<\/sub>] and FeCl<sub>3<\/sub> are verified as the best materials for preparation of Bronsted-Lewis acidic IL, and [Ps-MTH][CF<sub>3<\/sub>SO<sub>3<\/sub>]-FeCl<sub>3<\/sub>(x = 0.65) is determined as the most efficient catalyst in the end. The Lewis acidity, Bronsted acidity and interaction of [Ps-MTH][CF<sub>3<\/sub>SO<sub>3<\/sub>] and FeCl<sub>3<\/sub> in [Ps-MTH][CF<sub>3<\/sub>SO<sub>3<\/sub>]-FeCl<sub>3<\/sub>(x = 0.65) were characterized by FT-IR. And the catalytic mechanism of transesterification catalyzed by prepared IL was clarified. In order to maximize the biodiesel yield, optimization of process variables was conducted using Box-Behnken response surface methodol. The 97.04% of high biodiesel yield is obtained under the optimum conditions: reaction temperature was 127 \u00b0C, molar ratio (methanol to soapberry oil) was 27.96:1, catalyst amount was 3.06 mmol and reaction time was 8 h. Furthermore, [Ps-MTH][CF<sub>3<\/sub>SO<sub>3<\/sub>]-FeCl<sub>3<\/sub>(x = 0.65) presents good catalytic activity in different transesterification for biodiesel production And its catalytic activity decreases from 97.04% to 93.59% after being used for 5 times, which reflects good reusability. The main properties of soapberry biodiesel were also measured and compared to the ASTM D6751 standard<\/p>\n<p>Energy Conversion and Management published new progress about 930-36-9. 930-36-9 belongs to pyrazoles-derivatives, auxiliary class Pyrazole, name is 1-Methylpyrazole, and the molecular formula is C4H6N2, <a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Related Products of pyrazoles-derivatives<\/a>.<\/p>\n<p>Referemce:<br \/><a href=\"https:\/\/en.wikipedia.org\/wiki\/Pyrazole\">https:\/\/en.wikipedia.org\/wiki\/Pyrazole<\/a>,<br \/><a href=\"Pyrazole - Wikipedia\">Pyrazoles &#8211; an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Energy Conversion and Management published new progress about 930-36-9. 930-36-9 belongs to pyrazoles-derivatives, auxiliary class Pyrazole, name is 1-Methylpyrazole, and the molecular formula is C4H6N2, <a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Related Products of pyrazoles-derivatives<\/a>.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[245,131],"tags":[784],"class_list":["post-11703","post","type-post","status-publish","format-standard","hentry","category-930-36-9","category-pyrazoles-derivatives","tag-m-w50-100"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - 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