{"id":11447,"date":"2022-11-25T10:27:25","date_gmt":"2022-11-25T02:27:25","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=11447"},"modified":"2022-11-25T10:27:25","modified_gmt":"2022-11-25T02:27:25","slug":"turanov-alexander-n-s-team-published-research-in-polyhedron-in-161-cas-4551-69-3","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=11447","title":{"rendered":"Turanov, Alexander N.&#8217;s team published research in Polyhedron  in 161 | CAS: 4551-69-3"},"content":{"rendered":"<p>Turanov, Alexander N. published the artcile<b><i>Tripodal organophosphorus ligands as synergistic agents in the solvent extraction of lanthanides(III). Structure of mixed complexes and effect of diluents<\/i><\/b>,  <a href=\"https:\/\/www.ambeed.com\/products\/4551-69-3.html\">Computed Properties of  4551-69-3<\/a>,  the publication is  Polyhedron (2019), 276-288, database is CAplus.<\/p>\n<p>The solvent extraction of lanthanides (III) (except for Pm) from chloride medium (at \u03bc = 0.1) into an organic phase containing 4-benzoyl-3-methyl-1-phenyl-5-pyrazolone (HPy) and neutral tripodal ligands on the triphenylphosphine oxide platform with anchored carbamoyl side arms (2-R<sub>2<\/sub>NC(O)CH<sub>2<\/sub>OC<sub>6<\/sub>H<sub>4<\/sub>)<sub>3<\/sub>PO, where R = Bu (L1) and cyclo-Hex (L2) has been studied. A considerable synergistic effect (up to 10<sup>7<\/sup>) has been observed in the presence of neutral ligands L1 or L2 in the organic phase containing HPy. The stoichiometry of the Ln(III) extracted species has been determined by slope anal. and the equilibrium constants have been calculated It has been found that the lanthanides(III) ions are extracted with mixtures of HPy and neutral ligands L1 or L2 in toluene as LnPy<sub>3<\/sub>L species. The [LaPy<sub>3<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>], and new [LaPy<sub>3<\/sub>(L1)] and [LaPy<sub>3<\/sub>(L2)] complexes have been synthesized and characterized via elemental anal. and IR spectroscopy. Solution structure of the above complexes has been examined by IR and multinuclear (<sup>1<\/sup>H, <sup>13<\/sup>C, and <sup>31<\/sup>P) NMR spectroscopy in toluene-d<sub>8<\/sub> and CDCl<sub>3<\/sub>. The effect of diluents on synergistic extraction and the solution structure of mixed complexes are discussed.<\/p>\n<p>Polyhedron published new progress about 4551-69-3. 4551-69-3 belongs to pyrazoles-derivatives, auxiliary class Benzenes, name is 4-Benzoyl-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one, and the molecular formula is C11H14O2, <a href=\"https:\/\/www.ambeed.com\/products\/4551-69-3.html\">Computed Properties of  4551-69-3<\/a>.<\/p>\n<p>Referemce:<br \/><a href=\"https:\/\/en.wikipedia.org\/wiki\/Pyrazole\">https:\/\/en.wikipedia.org\/wiki\/Pyrazole<\/a>,<br \/><a href=\"Pyrazole - Wikipedia\">Pyrazoles &#8211; an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Polyhedron published new progress about 4551-69-3. 4551-69-3 belongs to pyrazoles-derivatives, auxiliary class Benzenes, name is 4-Benzoyl-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one, and the molecular formula is C11H14O2, <a href=\"https:\/\/www.ambeed.com\/products\/4551-69-3.html\">Computed Properties of  4551-69-3<\/a>.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[808,131],"tags":[740],"class_list":["post-11447","post","type-post","status-publish","format-standard","hentry","category-4551-69-3","category-pyrazoles-derivatives","tag-m-w250-300"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Turanov, Alexander N.&#039;s team published research in Polyhedron in 161 | CAS: 4551-69-3 | pyrazoles-derivatives<\/title>\n<meta name=\"description\" content=\"Turanov, Alexander N. published the artcileTripodal organophosphorus ligands as synergistic agents in the solvent extraction of lanthanides(III). Structure of mixed complexes and effect of diluents, Computed Properties of 4551-69-3, the publication is Polyhedron (2019), 276-288, database is CAplus.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.pyrazoles-derivatives.com\/?p=11447\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Turanov, Alexander N.&#039;s team published research in Polyhedron in 161 | CAS: 4551-69-3 | pyrazoles-derivatives\" \/>\n<meta property=\"og:description\" content=\"Turanov, Alexander N. published the artcileTripodal organophosphorus ligands as synergistic agents in the solvent extraction of lanthanides(III). Structure of mixed complexes and effect of diluents, Computed Properties of 4551-69-3, the publication is Polyhedron (2019), 276-288, database is CAplus.\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.pyrazoles-derivatives.com\/?p=11447\" \/>\n<meta property=\"og:site_name\" content=\"pyrazoles-derivatives\" \/>\n<meta property=\"article:published_time\" content=\"2022-11-25T02:27:25+00:00\" \/>\n<meta name=\"author\" content=\"Jessica.F\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Jessica.F\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minute\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11447\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11447\",\"name\":\"Turanov, Alexander N.'s team published research in Polyhedron in 161 | CAS: 4551-69-3 | pyrazoles-derivatives\",\"isPartOf\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\"},\"datePublished\":\"2022-11-25T02:27:25+00:00\",\"author\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1\"},\"description\":\"Turanov, Alexander N. published the artcileTripodal organophosphorus ligands as synergistic agents in the solvent extraction of lanthanides(III). Structure of mixed complexes and effect of diluents, Computed Properties of 4551-69-3, the publication is Polyhedron (2019), 276-288, database is CAplus.\",\"breadcrumb\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11447#breadcrumb\"},\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\/\/www.pyrazoles-derivatives.com\/?p=11447\"]}]},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11447#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"\u9996\u9875\",\"item\":\"https:\/\/www.pyrazoles-derivatives.com\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"Turanov, Alexander N.&#8217;s team published research in Polyhedron in 161 | CAS: 4551-69-3\"}]},{\"@type\":\"WebSite\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/\",\"name\":\"pyrazoles-derivatives\",\"description\":\"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. Pyrazole derivatives play an important role in antitumor agents.\",\"potentialAction\":[{\"@type\":\"SearchAction\",\"target\":{\"@type\":\"EntryPoint\",\"urlTemplate\":\"https:\/\/www.pyrazoles-derivatives.com\/?s={search_term_string}\"},\"query-input\":{\"@type\":\"PropertyValueSpecification\",\"valueRequired\":true,\"valueName\":\"search_term_string\"}}],\"inLanguage\":\"en-US\"},{\"@type\":\"Person\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1\",\"name\":\"Jessica.F\",\"image\":{\"@type\":\"ImageObject\",\"inLanguage\":\"en-US\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/image\/\",\"url\":\"https:\/\/weavatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g\",\"contentUrl\":\"https:\/\/weavatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g\",\"caption\":\"Jessica.F\"}}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Turanov, Alexander N.'s team published research in Polyhedron in 161 | CAS: 4551-69-3 | pyrazoles-derivatives","description":"Turanov, Alexander N. published the artcileTripodal organophosphorus ligands as synergistic agents in the solvent extraction of lanthanides(III). Structure of mixed complexes and effect of diluents, Computed Properties of 4551-69-3, the publication is Polyhedron (2019), 276-288, database is CAplus.","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/www.pyrazoles-derivatives.com\/?p=11447","og_locale":"en_US","og_type":"article","og_title":"Turanov, Alexander N.'s team published research in Polyhedron in 161 | CAS: 4551-69-3 | pyrazoles-derivatives","og_description":"Turanov, Alexander N. published the artcileTripodal organophosphorus ligands as synergistic agents in the solvent extraction of lanthanides(III). Structure of mixed complexes and effect of diluents, Computed Properties of 4551-69-3, the publication is Polyhedron (2019), 276-288, database is CAplus.","og_url":"https:\/\/www.pyrazoles-derivatives.com\/?p=11447","og_site_name":"pyrazoles-derivatives","article_published_time":"2022-11-25T02:27:25+00:00","author":"Jessica.F","twitter_card":"summary_large_image","twitter_misc":{"Written by":"Jessica.F","Est. reading time":"1 minute"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"WebPage","@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=11447","url":"https:\/\/www.pyrazoles-derivatives.com\/?p=11447","name":"Turanov, Alexander N.'s team published research in Polyhedron in 161 | CAS: 4551-69-3 | pyrazoles-derivatives","isPartOf":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/#website"},"datePublished":"2022-11-25T02:27:25+00:00","author":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1"},"description":"Turanov, Alexander N. published the artcileTripodal organophosphorus ligands as synergistic agents in the solvent extraction of lanthanides(III). Structure of mixed complexes and effect of diluents, Computed Properties of 4551-69-3, the publication is Polyhedron (2019), 276-288, database is CAplus.","breadcrumb":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=11447#breadcrumb"},"inLanguage":"en-US","potentialAction":[{"@type":"ReadAction","target":["https:\/\/www.pyrazoles-derivatives.com\/?p=11447"]}]},{"@type":"BreadcrumbList","@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=11447#breadcrumb","itemListElement":[{"@type":"ListItem","position":1,"name":"\u9996\u9875","item":"https:\/\/www.pyrazoles-derivatives.com\/"},{"@type":"ListItem","position":2,"name":"Turanov, Alexander N.&#8217;s team published research in Polyhedron in 161 | CAS: 4551-69-3"}]},{"@type":"WebSite","@id":"https:\/\/www.pyrazoles-derivatives.com\/#website","url":"https:\/\/www.pyrazoles-derivatives.com\/","name":"pyrazoles-derivatives","description":"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. Pyrazole derivatives play an important role in antitumor agents.","potentialAction":[{"@type":"SearchAction","target":{"@type":"EntryPoint","urlTemplate":"https:\/\/www.pyrazoles-derivatives.com\/?s={search_term_string}"},"query-input":{"@type":"PropertyValueSpecification","valueRequired":true,"valueName":"search_term_string"}}],"inLanguage":"en-US"},{"@type":"Person","@id":"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1","name":"Jessica.F","image":{"@type":"ImageObject","inLanguage":"en-US","@id":"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/image\/","url":"https:\/\/weavatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g","contentUrl":"https:\/\/weavatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g","caption":"Jessica.F"}}]}},"_links":{"self":[{"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/posts\/11447","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/users\/8"}],"replies":[{"embeddable":true,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=11447"}],"version-history":[{"count":0,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=\/wp\/v2\/posts\/11447\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=11447"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=11447"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.pyrazoles-derivatives.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=11447"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}