{"id":11354,"date":"2022-11-24T03:05:04","date_gmt":"2022-11-23T19:05:04","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=11354"},"modified":"2022-11-24T03:05:04","modified_gmt":"2022-11-23T19:05:04","slug":"lin-jiao-mins-team-published-research-in-science-china-chemistry-in-59-cas-19959-71-8","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=11354","title":{"rendered":"Lin, Jiao-Min&#8217;s team published research in Science China: Chemistry  in 59 | CAS: 19959-71-8"},"content":{"rendered":"<p>Lin, Jiao-Min published the artcile<b><i>A novel pillared-layer-type porous coordination polymer featuring three-dimensional pore system and high methane storage capacity<\/i><\/b>,  <a href=\"https:\/\/www.ambeed.com\/products\/19959-71-8.html\">Application In Synthesis of  19959-71-8<\/a>,  the publication is  Science China: Chemistry (2016), 59(8), 970-974, database is CAplus.<\/p>\n<p>Solvothermal reaction of Zn(NO<sub>3<\/sub>)<sub>2<\/sub>, 4-(1H-pyrazol-4-yl)pyridine (Hpypz) and 1,3,5-benzenetricarboxylic acid (H<sub>3<\/sub>btc) in N,N-dimethylacetamide (DMA) produced a new porous coordination polymer [Zn<sub>5<\/sub>(pypz)<sub>4<\/sub>(btc)<sub>2<\/sub>] (<strong>1<\/strong>). Single-crystal x-ray diffraction study of <strong>1<\/strong> showed that deprotonated pypz<sup>&#8211;<\/sup> ligands served as 1,2,4-triazolate-like ligands, linking Zn(II) ions to form porous 2D sql-a layers {Zn(pypz)}<sup>+<\/sup>, which were further connected by eight-legged pillars {Zn<sub>2<\/sub>(btc)<sub>4<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>}<sup>8-<\/sup> based on the typical paddlewheel dinuclear Zn<sub>2<\/sub>(RCOO)<sub>4<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub> cluster to form a novel type of noninterpenetrated pillared-layer framework with 3D intersecting pore system and large pore volume Gas sorption measurements revealed that <strong>1<\/strong> possesses a large BET surface area of 2061 m<sup>2<\/sup> g<sup>-1<\/sup> and very high methane total uptake of 245 cm<sup>3<\/sup>(STP) cm<sup>-3<\/sup> at 298 K and 65 bar.<\/p>\n<p>Science China: Chemistry published new progress about 19959-71-8. 19959-71-8 belongs to pyrazoles-derivatives, auxiliary class Pyrazole,Pyridine, name is 4-(1H-Pyrazol-4-yl)pyridine, and the molecular formula is C8H7N3, <a href=\"https:\/\/www.ambeed.com\/products\/19959-71-8.html\">Application In Synthesis of  19959-71-8<\/a>.<\/p>\n<p>Referemce:<br \/><a href=\"https:\/\/en.wikipedia.org\/wiki\/Pyrazole\">https:\/\/en.wikipedia.org\/wiki\/Pyrazole<\/a>,<br \/><a href=\"Pyrazole - Wikipedia\">Pyrazoles &#8211; an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Science China: Chemistry published new progress about 19959-71-8. 19959-71-8 belongs to pyrazoles-derivatives, auxiliary class Pyrazole,Pyridine, name is 4-(1H-Pyrazol-4-yl)pyridine, and the molecular formula is C8H7N3, <a href=\"https:\/\/www.ambeed.com\/products\/19959-71-8.html\">Application In Synthesis of  19959-71-8<\/a>.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[803,131],"tags":[732],"class_list":["post-11354","post","type-post","status-publish","format-standard","hentry","category-19959-71-8","category-pyrazoles-derivatives","tag-m-w100-150"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Lin, Jiao-Min&#039;s team published research in Science China: Chemistry in 59 | CAS: 19959-71-8 | pyrazoles-derivatives<\/title>\n<meta name=\"description\" content=\"Lin, Jiao-Min published the artcileA novel pillared-layer-type porous coordination polymer featuring three-dimensional pore system and high methane storage capacity, Application In Synthesis of 19959-71-8, the publication is Science China: Chemistry (2016), 59(8), 970-974, database is CAplus.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.pyrazoles-derivatives.com\/?p=11354\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Lin, Jiao-Min&#039;s team published research in Science China: Chemistry in 59 | CAS: 19959-71-8 | pyrazoles-derivatives\" \/>\n<meta property=\"og:description\" content=\"Lin, Jiao-Min published the artcileA novel pillared-layer-type porous coordination polymer featuring three-dimensional pore system and high methane storage capacity, Application In Synthesis of 19959-71-8, the publication is Science China: Chemistry (2016), 59(8), 970-974, database is CAplus.\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.pyrazoles-derivatives.com\/?p=11354\" \/>\n<meta property=\"og:site_name\" content=\"pyrazoles-derivatives\" \/>\n<meta property=\"article:published_time\" content=\"2022-11-23T19:05:04+00:00\" \/>\n<meta name=\"author\" content=\"Jessica.F\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Jessica.F\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minute\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11354\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11354\",\"name\":\"Lin, Jiao-Min's team published research in Science China: Chemistry in 59 | CAS: 19959-71-8 | pyrazoles-derivatives\",\"isPartOf\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\"},\"datePublished\":\"2022-11-23T19:05:04+00:00\",\"author\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1\"},\"description\":\"Lin, Jiao-Min published the artcileA novel pillared-layer-type porous coordination polymer featuring three-dimensional pore system and high methane storage capacity, Application In Synthesis of 19959-71-8, the publication is Science China: Chemistry (2016), 59(8), 970-974, database is CAplus.\",\"breadcrumb\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11354#breadcrumb\"},\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\/\/www.pyrazoles-derivatives.com\/?p=11354\"]}]},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11354#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"\u9996\u9875\",\"item\":\"https:\/\/www.pyrazoles-derivatives.com\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"Lin, Jiao-Min&#8217;s team published research in Science China: Chemistry in 59 | CAS: 19959-71-8\"}]},{\"@type\":\"WebSite\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/\",\"name\":\"pyrazoles-derivatives\",\"description\":\"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. 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