{"id":11237,"date":"2022-11-21T05:06:50","date_gmt":"2022-11-20T21:06:50","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=11237"},"modified":"2022-11-21T05:06:50","modified_gmt":"2022-11-20T21:06:50","slug":"zhang-pengfeis-team-published-research-in-asian-journal-of-chemistry-in-26-cas-4551-69-3","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=11237","title":{"rendered":"Zhang, Pengfei’s team published research in Asian Journal of Chemistry in 26 | CAS: 4551-69-3"},"content":{"rendered":"

Zhang, Pengfei published the artcileSynthesis, crystal structure and quantum chemistry calculation of two novel compounds derived from amino-phenol<\/i><\/b>, Synthetic Route of 4551-69-3<\/a>, the publication is Asian Journal of Chemistry (2014), 26(18), 6176-6184, database is CAplus.<\/p>\n

Two novel compounds [(Z)-3-(2-hydroxy-4-methylphenylimino)indolin-2-one][methanol] (A) and 4-[(Z)-(3-hydroxy-4-methoxyphenylimino)(phenyl)methyl]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one (B) derived from aminophenol were synthesized and characterized by IR spectroscopy, elemental anal. and X-ray diffraction single-crystal anal. Compound A crystallized in monoclinic space group P21\/c with a = 15.6637 (12) \u00b0, b = 12.3527 (9) \u00b0, c = 7.4461 (6) \u00b0, \u03b1 = 90\u00b0, \u03b2 = 100.9460 (10)\u00b0, \u03b3 = 90\u00b0, V = 1414.53 (19) nm3<\/sup>, Z = 4, F (000) = 600, S = 1.055, R1<\/sub> = 0392, wR2<\/sub> = 0.0967. Compound B crystallized in triclinic, space group P-1 with a = 8.8111 (9) \u00b0, b = 11.4716 (12) \u00b0, c = 11.4947 (14) \u00b0, \u03b1 = 115.376 (2)\u00b0, \u03b2 = 99.5470 (10)\u00b0, \u03b3 = 97.6320 (10)\u00b0, V = 1007.74 (19) nm3<\/sup>, Z = 2, F (000) = 420, S = 1.046, R1<\/sub> = 0.0643, wR2<\/sub> = 0.1479. Theor. studies of compounds A and B were carried out by d. functional theory B3LYP method. The results showed that N (1), O (1) and O (2) of compound A and N (3), O (1) and O (2) of compound B were major active sites. Furthermore, N (1) in compound A was preferentially attacked by nucleophilic, followed by the N (3) in compound B. The theor. studies showed that compound A may have higher biol. activity, such as anti-proliferative activity, compared with compound B. The result might be because that compound A was Schiff base and compound B showed proton transfer and tautomerism.<\/p>\n

Asian Journal of Chemistry published new progress about 4551-69-3. 4551-69-3 belongs to pyrazoles-derivatives, auxiliary class Benzenes, name is 4-Benzoyl-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one, and the molecular formula is C44H28ClFeN4, Synthetic Route of 4551-69-3<\/a>.<\/p>\n

Referemce:
https:\/\/en.wikipedia.org\/wiki\/Pyrazole<\/a>,
Pyrazoles – an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

Asian Journal of Chemistry published new progress about 4551-69-3. 4551-69-3 belongs to pyrazoles-derivatives, auxiliary class Benzenes, name is 4-Benzoyl-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one, and the molecular formula is C44H28ClFeN4, Synthetic Route of 4551-69-3<\/a>.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[131],"tags":[740],"class_list":["post-11237","post","type-post","status-publish","format-standard","hentry","category-pyrazoles-derivatives","tag-m-w250-300"],"yoast_head":"\nZhang, Pengfei's team published research in Asian Journal of Chemistry in 26 | CAS: 4551-69-3 | pyrazoles-derivatives<\/title>\n<meta name=\"description\" content=\"Zhang, Pengfei published the artcileSynthesis, crystal structure and quantum chemistry calculation of two novel compounds derived from amino-phenol, Synthetic Route of 4551-69-3, the publication is Asian Journal of Chemistry (2014), 26(18), 6176-6184, database is CAplus.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.pyrazoles-derivatives.com\/?p=11237\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Zhang, Pengfei's team published research in Asian Journal of Chemistry in 26 | CAS: 4551-69-3 | pyrazoles-derivatives\" \/>\n<meta property=\"og:description\" content=\"Zhang, Pengfei published the artcileSynthesis, crystal structure and quantum chemistry calculation of two novel compounds derived from amino-phenol, Synthetic Route of 4551-69-3, the publication is Asian Journal of Chemistry (2014), 26(18), 6176-6184, database is CAplus.\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.pyrazoles-derivatives.com\/?p=11237\" \/>\n<meta property=\"og:site_name\" content=\"pyrazoles-derivatives\" \/>\n<meta property=\"article:published_time\" content=\"2022-11-20T21:06:50+00:00\" \/>\n<meta name=\"author\" content=\"Jessica.F\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Jessica.F\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minute\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11237\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11237\",\"name\":\"Zhang, Pengfei's team published research in Asian Journal of Chemistry in 26 | CAS: 4551-69-3 | pyrazoles-derivatives\",\"isPartOf\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\"},\"datePublished\":\"2022-11-20T21:06:50+00:00\",\"author\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1\"},\"description\":\"Zhang, Pengfei published the artcileSynthesis, crystal structure and quantum chemistry calculation of two novel compounds derived from amino-phenol, Synthetic Route of 4551-69-3, the publication is Asian Journal of Chemistry (2014), 26(18), 6176-6184, database is CAplus.\",\"breadcrumb\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11237#breadcrumb\"},\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\/\/www.pyrazoles-derivatives.com\/?p=11237\"]}]},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=11237#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"\u9996\u9875\",\"item\":\"https:\/\/www.pyrazoles-derivatives.com\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"Zhang, Pengfei’s team published research in Asian Journal of Chemistry in 26 | CAS: 4551-69-3\"}]},{\"@type\":\"WebSite\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/\",\"name\":\"pyrazoles-derivatives\",\"description\":\"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. 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