{"id":10959,"date":"2022-11-14T04:01:01","date_gmt":"2022-11-13T20:01:01","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=10959"},"modified":"2022-11-14T04:01:01","modified_gmt":"2022-11-13T20:01:01","slug":"perkins-robert-j-s-team-published-research-in-organic-letters-in-2017-07-21-cas-116228-41-2","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=10959","title":{"rendered":"Perkins, Robert J.&#8217;s team published research in Organic Letters  in 2017-07-21 | CAS: 116228-41-2"},"content":{"rendered":"<p>Perkins, Robert J. published the artcile<b><i>Electrochemical Nickel Catalysis for Sp2-Sp3 Cross-Electrophile Coupling Reactions of Unactivated Alkyl Halides<\/i><\/b>,  <a href=\"https:\/\/www.ambeed.com\/products\/116228-41-2.html\">Product Details of C10H9BrN2O2S<\/a>,  the main research area is  electrochem nickel catalysis electrophile coupling reaction alkyl halide.<\/p>\n<p>A constant-current electrochem. method for reducing catalytic Ni complexes in sp2-sp3 cross-electrophile coupling reactions was developed. The electrochem. reduction provides reliable Ni catalyst activation and turnover and offers a tunable parameter for reaction optimization, in contrast to more standard activated metal powder reductants. The electrochem. reactions give yields (i.e., 51-86%) and selectivities as high or superior to those using metal powder reductants and provide access to a wider substrate scope.<\/p>\n<p>Organic Letters published new progress about Coupling reaction catalysts (electrochem.). 116228-41-2 belongs to class pyrazoles-derivatives, name is 4-Bromo-1-tosyl-1H-pyrazole, and the molecular formula is C10H9BrN2O2S, <a href=\"https:\/\/www.ambeed.com\/products\/116228-41-2.html\">Product Details of C10H9BrN2O2S<\/a>.<\/p>\n<p>Referemce:<br \/><a href=\"https:\/\/en.wikipedia.org\/wiki\/Pyrazole\">Pyrazole &#8211; Wikipedia<\/a>,<br \/><a href=\"https:\/\/www.sciencedirect.com\/topics\/chemistry\/pyrazoles\">Pyrazoles &#8211; an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Organic Letters published new progress about Coupling reaction catalysts (electrochem.). 116228-41-2 belongs to class pyrazoles-derivatives, name is 4-Bromo-1-tosyl-1H-pyrazole, and the molecular formula is C10H9BrN2O2S, <a href=\"https:\/\/www.ambeed.com\/products\/116228-41-2.html\">Product Details of C10H9BrN2O2S<\/a>.<\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[777,131],"tags":[778],"class_list":["post-10959","post","type-post","status-publish","format-standard","hentry","category-116228-41-2","category-pyrazoles-derivatives","tag-m-w200-350"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - 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