{"id":10466,"date":"2022-10-21T06:58:52","date_gmt":"2022-10-20T22:58:52","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=10466"},"modified":"2022-10-21T06:58:52","modified_gmt":"2022-10-20T22:58:52","slug":"zhang-jingshuns-team-published-research-in-molecular-catalysis-in-2019-cas-930-36-9","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=10466","title":{"rendered":"Zhang, Jingshun&#8217;s team published research in Molecular Catalysis in 2019 | CAS: 930-36-9"},"content":{"rendered":"<p>\u300aCombination of experimental and theoretical methods to explore the amino-functionalized pyrazolium ionic liquids: An efficient single-component catalyst for chemical fixation of CO2 under mild conditions\u300b was written by Zhang, Jingshun; Zhu, Xinrui; Fan, Baowan; Guo, Jia; Ning, Pan; Ren, Tiegang; Wang, Li; Zhang, Jinglai. <a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Recommanded Product: 930-36-9<\/a> And the article was included in Molecular Catalysis on April 30 ,2019. The article conveys some information:<\/p>\n<p>Four new amino-functionalized pyrazolium ionic liquids, I [R = Me, Et; n = 1, 2] were firstly synthesized in simple reaction steps with cheap raw materials. Ionic liquids I would catalyze the coupling reaction of carbon dioxide with propyleneoxide under optimal reaction conditions, 110 \u00b0C, 1.5 MPa carbon dioxide initial pressure as well as 1.0 mol% catalyst amount for 4.0 h, with propylene carbonate yield over 94%. The reaction temperature was decreased by 10-20 \u00b0C as compared with other single-component ionic liquids and at the same time, carbon dioxide initial pressure was not increased to keep 1.5 MPa. The recyclability and suitability of amino-functionalized pyrazolium ionic liquids were explored and catalytic mechanism was investigated by d. functional theory. Moreover, the influence of weak interactions on reaction was analyzed by atoms in mols. and non-covalent interactions. As compared with other reported ionic liquids, the reaction condition catalyzed by ionic liquid I [R = Et, n = 2] was more benign with comparable product yield. More importantly, there was good balance among various reaction conditions without sacrificing one to ensure others. In addition to this study using 1-Methylpyrazole, there are many other studies that have used 1-Methylpyrazole(cas: 930-36-9<a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Recommanded Product: 930-36-9<\/a>) was used in this study.<\/p>\n<p>1-Methylpyrazole(cas: 930-36-9) belongs to pyrazoles. Pyrazole derivatives have been reported to exhibit a wide range of applications in medicinal chemistry and pharmacology. A large number of drugs incorporating pyrazole structure have been utilized as partial agonists for nicotinic acid receptors, antidepressants, antimicrobial agents, antiviral agents, and antifungal agents solely or along with the combination of other structural motifs.<a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Recommanded Product: 930-36-9<\/a><\/p>\n<p>Referemce:<br \/><a href=\"https:\/\/en.wikipedia.org\/wiki\/Pyrazole\">Pyrazole &#8211; Wikipedia<\/a>,<br \/><a href=\"https:\/\/www.sciencedirect.com\/topics\/chemistry\/pyrazoles\">Pyrazoles &#8211; an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>1-Methylpyrazole(cas: 930-36-9) belongs to pyrazoles. Pyrazole derivatives have been reported to exhibit a wide range of applications in medicinal chemistry and pharmacology. A large number of drugs incorporating pyrazole structure have been utilized as partial agonists for nicotinic acid receptors, antidepressants, antimicrobial agents, antiviral agents, and antifungal agents solely or along with the combination of other structural motifs.<a href=\"https:\/\/www.ambeed.com\/products\/930-36-9.html\">Recommanded Product: 930-36-9<\/a><\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[245,131],"tags":[743],"class_list":["post-10466","post","type-post","status-publish","format-standard","hentry","category-930-36-9","category-pyrazoles-derivatives","tag-0-100"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v24.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Zhang, Jingshun&#039;s team published research in Molecular Catalysis in 2019 | CAS: 930-36-9 | pyrazoles-derivatives<\/title>\n<meta name=\"description\" content=\"\u300aCombination of experimental and theoretical methods to explore the amino-functionalized pyrazolium ionic liquids: An efficient single-component catalyst for chemical fixation of CO2 under mild conditions\u300b was written by Zhang, Jingshun; Zhu, Xinrui; Fan, Baowan; Guo, Jia; Ning, Pan; Ren, Tiegang; Wang, Li; Zhang, Jinglai. Recommanded Product: 930-36-9 And the article was included in Molecular Catalysis on April 30 ,2019. The article conveys some information:\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.pyrazoles-derivatives.com\/?p=10466\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Zhang, Jingshun&#039;s team published research in Molecular Catalysis in 2019 | CAS: 930-36-9 | pyrazoles-derivatives\" \/>\n<meta property=\"og:description\" content=\"\u300aCombination of experimental and theoretical methods to explore the amino-functionalized pyrazolium ionic liquids: An efficient single-component catalyst for chemical fixation of CO2 under mild conditions\u300b was written by Zhang, Jingshun; Zhu, Xinrui; Fan, Baowan; Guo, Jia; Ning, Pan; Ren, Tiegang; Wang, Li; Zhang, Jinglai. Recommanded Product: 930-36-9 And the article was included in Molecular Catalysis on April 30 ,2019. 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