{"id":10335,"date":"2022-10-20T04:13:01","date_gmt":"2022-10-19T20:13:01","guid":{"rendered":"https:\/\/www.pyrazoles-derivatives.com\/?p=10335"},"modified":"2022-10-20T04:13:01","modified_gmt":"2022-10-19T20:13:01","slug":"chandrasekhar-vadapallis-team-published-research-in-inorganic-chemistry-in-2012-cas-20154-03-4","status":"publish","type":"post","link":"https:\/\/www.pyrazoles-derivatives.com\/?p=10335","title":{"rendered":"Chandrasekhar, Vadapalli’s team published research in Inorganic Chemistry in 2012 | CAS: 20154-03-4"},"content":{"rendered":"

In 2012,Chandrasekhar, Vadapalli; Nagarajan, Loganathan; Hossain, Sakiat; Gopal, Kandasamy; Ghosh, Surajit; Verma, Sandeep published \u300aMulticomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages\u300b.Inorganic Chemistry published the findings.HPLC of Formula: 20154-03-4<\/a> The information in the text is summarized as follows:<\/p>\n

A multicomponent synthetic strategy involving Cu(II) ions, tert-butylphosphonic acid (t-BuPO3H2) and 3-substituted pyrazole ligands was adopted for the synthesis of soluble mol. Cu(II) phosphonates. The use of six different 3-substituted pyrazoles, 3-R-PzH [R = H, Me, CF3, Ph, 2-pyridyl (2-Py), and 2-methoxyphenyl (2-MeO-C6H4)] as ancillary ligands afforded nine different decanuclear cages, [Cu5(\u03bc3-OH)2(O3P-t-Bu)3(3-R-Pz)2(X)2]2\u00b7(Y) where R = H, X = t-BuPO3H, and Y = (Et3NH+)4(solvent) (1); R = Me, X = 3-MePzH, and Y = solvent (2); R = Me, X = t-BuPO3H, and Y = (Et3NH+)4(solvent) (3); R = CF3, X = t-BuPO3H, and Y = (Et3NH+)4(solvent) (4); R = Ph, X = 3-PhPzH, and Y = solvent (5); R = 2-Py, X = 0.5 MeOH, and Y = solvent (6); R = 2-Py, X = none, and Y = solvent (7); R = 2-Py, X = H2O, and Y = (Et3NH+\u00b7PF6-)2(solvent) (8); R = 2-MeO-C6H4, X = MeOH or 0.5:0.5 MeOH\/H2O, and Y = solvent (9). Compounds 1-6, 8, and 9 were isolated using a direct synthetic method which involves the reaction of Cu(II) salts and the ligands, while 7 was obtained from an indirect route involving the reaction of preformed Cu-pyridylpyrazolate precursor complexes and t-BuPO3H2. The decametallic compounds 1-9 possess a butterfly-shaped core. The core of the cages 1, 3, and 4 are tetraanionic and contain more phosphonates than pyrazole ligands, while the other cages are neutral and contain more pyrazoles than phosphonate ligands. Compounds 1-6 were studied by electrospray ionization-high-resolution mass spectrometry (ESI-HRMS). The decanuclear cage 6 is a good plasmid modifier. The experimental part of the paper was very detailed, including the reaction process of 3-(Trifluoromethyl)-1H-pyrazole(cas: 20154-03-4HPLC of Formula: 20154-03-4<\/a>)<\/p>\n

3-(Trifluoromethyl)-1H-pyrazole(cas: 20154-03-4) belongs to pyrazoles. The application of pyrazole derivatives in the development of anticancer agents has been thoroughly investigated and verified. Moreover, the medicinal features of a number of natural products incorporating pyrazole moiety such as pyrazofurin, pyrazofurin B, pyrazole-3(5)-carboxylic acid and 4-methylpyrazole-3(5)-carboxylic acid have been reported.HPLC of Formula: 20154-03-4<\/a><\/p>\n

Referemce:
Pyrazole – Wikipedia<\/a>,
Pyrazoles – an overview | ScienceDirect Topics<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

3-(Trifluoromethyl)-1H-pyrazole(cas: 20154-03-4) belongs to pyrazoles. The application of pyrazole derivatives in the development of anticancer agents has been thoroughly investigated and verified. Moreover, the medicinal features of a number of natural products incorporating pyrazole moiety such as pyrazofurin, pyrazofurin B, pyrazole-3(5)-carboxylic acid and 4-methylpyrazole-3(5)-carboxylic acid have been reported.HPLC of Formula: 20154-03-4<\/a><\/p>\n","protected":false},"author":8,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[205,131],"tags":[128],"class_list":["post-10335","post","type-post","status-publish","format-standard","hentry","category-20154-03-4","category-pyrazoles-derivatives","tag-100-200"],"yoast_head":"\nChandrasekhar, Vadapalli's team published research in Inorganic Chemistry in 2012 | CAS: 20154-03-4 | pyrazoles-derivatives<\/title>\n<meta name=\"description\" content=\"In 2012,Chandrasekhar, Vadapalli; Nagarajan, Loganathan; Hossain, Sakiat; Gopal, Kandasamy; Ghosh, Surajit; Verma, Sandeep published \u300aMulticomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages\u300b.Inorganic Chemistry published the findings.HPLC of Formula: 20154-03-4 The information in the text is summarized as follows:\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.pyrazoles-derivatives.com\/?p=10335\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Chandrasekhar, Vadapalli's team published research in Inorganic Chemistry in 2012 | CAS: 20154-03-4 | pyrazoles-derivatives\" \/>\n<meta property=\"og:description\" content=\"In 2012,Chandrasekhar, Vadapalli; Nagarajan, Loganathan; Hossain, Sakiat; Gopal, Kandasamy; Ghosh, Surajit; Verma, Sandeep published \u300aMulticomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages\u300b.Inorganic Chemistry published the findings.HPLC of Formula: 20154-03-4 The information in the text is summarized as follows:\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.pyrazoles-derivatives.com\/?p=10335\" \/>\n<meta property=\"og:site_name\" content=\"pyrazoles-derivatives\" \/>\n<meta property=\"article:published_time\" content=\"2022-10-19T20:13:01+00:00\" \/>\n<meta name=\"author\" content=\"Jessica.F\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Jessica.F\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"2 minutes\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=10335\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=10335\",\"name\":\"Chandrasekhar, Vadapalli's team published research in Inorganic Chemistry in 2012 | CAS: 20154-03-4 | pyrazoles-derivatives\",\"isPartOf\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\"},\"datePublished\":\"2022-10-19T20:13:01+00:00\",\"author\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1\"},\"description\":\"In 2012,Chandrasekhar, Vadapalli; Nagarajan, Loganathan; Hossain, Sakiat; Gopal, Kandasamy; Ghosh, Surajit; Verma, Sandeep published \u300aMulticomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages\u300b.Inorganic Chemistry published the findings.HPLC of Formula: 20154-03-4 The information in the text is summarized as follows:\",\"breadcrumb\":{\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=10335#breadcrumb\"},\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\/\/www.pyrazoles-derivatives.com\/?p=10335\"]}]},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/?p=10335#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"\u9996\u9875\",\"item\":\"https:\/\/www.pyrazoles-derivatives.com\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"Chandrasekhar, Vadapalli’s team published research in Inorganic Chemistry in 2012 | CAS: 20154-03-4\"}]},{\"@type\":\"WebSite\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#website\",\"url\":\"https:\/\/www.pyrazoles-derivatives.com\/\",\"name\":\"pyrazoles-derivatives\",\"description\":\"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. Pyrazole derivatives play an important role in antitumor agents.\",\"potentialAction\":[{\"@type\":\"SearchAction\",\"target\":{\"@type\":\"EntryPoint\",\"urlTemplate\":\"https:\/\/www.pyrazoles-derivatives.com\/?s={search_term_string}\"},\"query-input\":{\"@type\":\"PropertyValueSpecification\",\"valueRequired\":true,\"valueName\":\"search_term_string\"}}],\"inLanguage\":\"en-US\"},{\"@type\":\"Person\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1\",\"name\":\"Jessica.F\",\"image\":{\"@type\":\"ImageObject\",\"inLanguage\":\"en-US\",\"@id\":\"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/image\/\",\"url\":\"https:\/\/en.cravatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g\",\"contentUrl\":\"https:\/\/en.cravatar.com\/avatar\/2d1cec2a99eeaad5a5b217c9cdbfb610?s=96&d=mm&r=g\",\"caption\":\"Jessica.F\"}}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Chandrasekhar, Vadapalli's team published research in Inorganic Chemistry in 2012 | CAS: 20154-03-4 | pyrazoles-derivatives","description":"In 2012,Chandrasekhar, Vadapalli; Nagarajan, Loganathan; Hossain, Sakiat; Gopal, Kandasamy; Ghosh, Surajit; Verma, Sandeep published \u300aMulticomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages\u300b.Inorganic Chemistry published the findings.HPLC of Formula: 20154-03-4 The information in the text is summarized as follows:","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/www.pyrazoles-derivatives.com\/?p=10335","og_locale":"en_US","og_type":"article","og_title":"Chandrasekhar, Vadapalli's team published research in Inorganic Chemistry in 2012 | CAS: 20154-03-4 | pyrazoles-derivatives","og_description":"In 2012,Chandrasekhar, Vadapalli; Nagarajan, Loganathan; Hossain, Sakiat; Gopal, Kandasamy; Ghosh, Surajit; Verma, Sandeep published \u300aMulticomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages\u300b.Inorganic Chemistry published the findings.HPLC of Formula: 20154-03-4 The information in the text is summarized as follows:","og_url":"https:\/\/www.pyrazoles-derivatives.com\/?p=10335","og_site_name":"pyrazoles-derivatives","article_published_time":"2022-10-19T20:13:01+00:00","author":"Jessica.F","twitter_card":"summary_large_image","twitter_misc":{"Written by":"Jessica.F","Est. reading time":"2 minutes"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"WebPage","@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=10335","url":"https:\/\/www.pyrazoles-derivatives.com\/?p=10335","name":"Chandrasekhar, Vadapalli's team published research in Inorganic Chemistry in 2012 | CAS: 20154-03-4 | pyrazoles-derivatives","isPartOf":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/#website"},"datePublished":"2022-10-19T20:13:01+00:00","author":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/#\/schema\/person\/d9a9f27bed675392c6f363a01ffd49f1"},"description":"In 2012,Chandrasekhar, Vadapalli; Nagarajan, Loganathan; Hossain, Sakiat; Gopal, Kandasamy; Ghosh, Surajit; Verma, Sandeep published \u300aMulticomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages\u300b.Inorganic Chemistry published the findings.HPLC of Formula: 20154-03-4 The information in the text is summarized as follows:","breadcrumb":{"@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=10335#breadcrumb"},"inLanguage":"en-US","potentialAction":[{"@type":"ReadAction","target":["https:\/\/www.pyrazoles-derivatives.com\/?p=10335"]}]},{"@type":"BreadcrumbList","@id":"https:\/\/www.pyrazoles-derivatives.com\/?p=10335#breadcrumb","itemListElement":[{"@type":"ListItem","position":1,"name":"\u9996\u9875","item":"https:\/\/www.pyrazoles-derivatives.com\/"},{"@type":"ListItem","position":2,"name":"Chandrasekhar, Vadapalli’s team published research in Inorganic Chemistry in 2012 | CAS: 20154-03-4"}]},{"@type":"WebSite","@id":"https:\/\/www.pyrazoles-derivatives.com\/#website","url":"https:\/\/www.pyrazoles-derivatives.com\/","name":"pyrazoles-derivatives","description":"Several pyrazole derivatives possess important pharmacological activities and they have been proved useful materials in drug research. 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