Tag: M.W=0-100

Wang, TF; Kosuru, SR; Yu, SC; Chang, YC; Lai, HY; Chang, YL; Wu, KH; Ding, SW; Chen, HY in [Wang, Tzu-Fang; Kosuru, Someswara Rao; Yu, Shu-Chun; Chang, Yung-Chi; Lai, Hsin-Yu; Chang, Yu-Lun; Ding, Shangwu; Chen, Hsuan-Ying] Kaohsiung Med Univ, Drug Dev & Value Creat Res Ctr, Dept Med & Appl Chem, Kaohsiung 80708, Taiwan; [Wu, Kuo-Hui] Univ Tokyo, Grad Sch Sci, Dept Chem, Tokyo 1130033, Japan; [Wu, Kuo-Hui] Tamkang Univ, Dept Chem, Tamsui 251, Taiwan; [Ding, Shangwu; Chen, Hsuan-Ying] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 80424, Taiwan; [Chen, Hsuan-Ying] Kaohsiung Med Univ Hosp, Dept Med Res, Kaohsiung 80708, Taiwan published Use of pyrazoles as ligands greatly enhances the catalytic activity of titanium iso-propoxide for the ring-opening polymerization of l-lactide: a cooperation effect in 2020.0, Cited 69.0. Recommanded Product: 67-51-6. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.

Using TiOⁱPr4 with a pyrazole ligand for one-pot LA polymerization improved catalytic activity compared with using TiOⁱPr4 only. At 60 degrees C, TiOⁱPr4 with ^furPz exhibited a higher catalytic activity (approximately 3-fold) than TiOⁱPr4. At room temperature, TiOⁱPr4 with ^BuPz exhibited a higher catalytic activity (approximately 17-fold) than TiOⁱPr4. High molecular mass PLA (MnGPC = 51 100, and D = 1.10) could be produced by using TiOⁱPr4 with ^furPz in melt polymerization ([TiOⁱPr4] : [^furPz] = 1000 : 1 : 1 at 100 degrees C, 240 min). The crystal structure of ^MePz2Ti2OⁱPr7 revealed the cooperative activation between two Ti atoms during LA polymerization.

Recommanded Product: 67-51-6. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Wang, TF; Kosuru, SR; Yu, SC; Chang, YC; Lai, HY; Chang, YL; Wu, KH; Ding, SW; Chen, HY or concate me.

Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics

Application In Synthesis of 3,5-Dimethyl-1H-pyrazole. In 2020.0 ORG LETT published article about 2+2 PHOTOCYCLOADDITION REACTIONS; ENANTIOSELECTIVE SYNTHESIS; CASCADE REACTION; CYCLOADDITION; CATALYSIS; ENALS in [Chen, Yuzhen; Wang, Yichen; Wang, Shuzhong; Zhan, Ruoting; Huang, Huicai] Guangzhou Univ Chinese Med, Res Ctr Chinese Herbal Resource Sci & Engn, Key Lab Chinese Med Resource Lingnan, Minist Educ, Guangzhou 510006, Peoples R China; [Ma, Yan-Yan; Zhao, Deng-Gao] Wuyi Univ, Sch Biotechnol & Hlth Sci, Jiangmen 529020, Peoples R China in 2020.0, Cited 48.0. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.

The construction of cyclobutanes has attracted much attention because of its unique four-membered ring skeleton. Herein, we report the highly enantioselective direct vinylogous Michael reaction of beta,gamma-unsaturated pyrazole amides and nitroolefin using a squaramide catalyst. Cyclobutane derivatives were obtained by subsequent cyclization in good yields (up to 85%) with excellent enantioselectivities (up to 99% ee). Importantly, the large-scale reaction experiment confirmed the reliability of the vinylogous reaction. Furthermore, the synthetic utility of the vinylogous adducts and cyclobutane derivatives has been realized.

Application In Synthesis of 3,5-Dimethyl-1H-pyrazole. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Chen, YZ; Wang, YC; Wang, SZ; Ma, YY; Zhao, DG; Zhan, RT; Huang, HC or concate me.

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Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics

An article Nickel(II) complexes with tripodal NNN ligands as homogenous and supported catalysts for ethylene oligomerization WOS:000456751700004 published article about BRANCHED POLYETHYLENE; FUNCTIONALIZED POLYOLEFINS; ALKYLALUMINUM COCATALYST; METAL-COMPLEXES; NITROGEN DONOR; AMINE LIGANDS; POLYMERIZATION; ALUMINUM; NMR; TEMPERATURE in [Tuskaev, Vladislav A.; Zubkevich, Sergei V.; Gagieva, Svetlana Ch.; Bulychev, Boris M.] Moscow MV Lomonosov State Univ, Chem Dept, Leninskie Gory 11, Moscow 119991, Russia; [Tuskaev, Vladislav A.; Kononova, Elena G.; Khrustalev, Victor N.; Zarubin, Dmitry N.] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov Str 28, Moscow 119991, Russia; [Saracheno, Daniele] Dimitri Mendeleev Univ Chem Technol Russia, Higher Coll Chem Russia, Miusskaya Sq 9, Moscow 125047, Russia; [Dorovatovskii, Pavel V.; Khrustalev, Victor N.] Natl Res Ctr, Kurchatov Inst, Moscow, Russia; [Khrustalev, Victor N.] Peoples Friendship Univ Russia RUDN, Moscow, Russia; [Kissin, Yury V.] Rutgers State Univ, Dept Chem & Chem Biol, 123 Bevier Rd, Piscataway, NJ 08854 USA in 2019.0, Cited 73.0. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6. Safety of 3,5-Dimethyl-1H-pyrazole

Four new coordination compounds of nickel (II) with derivatives of N,N-bis(pyrazol-1-ylmethyl)propylamine were synthesized; their composition and structure were confirmed with IR-spectroscopy and elemental analysis. The structures of products 13 and 15 were unambiguously established in an X-ray diffraction study. Compounds 13 and 15 crystallize in the orthorhombic space groups Pna2(1) and P2(1)2(1)2(1) correspondingly and represent a monomeric octahedral nickel complexes, that are typical for tridentate scorpion-type ligands. New method for immobilization of nickel complexes with derivatives of N,N-bis(pyrazol-1-ylmethyl)propylamine on silica gel modified with aminopropyl groups was proposed. The EXAFS/XANES analysis indicated that Ni atom in the supported complexes adopt almost octahedral geometry, being partly surrounded by nitrogen atoms from organic ligand and partly grafted to silica surface through silanol groups, with Br- in outer coordination sphere. Both the original and the supported complexes, when activated with Et2AlCl or Et3Al2Cl3, catalyze ethylene oligomerization with the predominant formation of butene isomers. Generally, the immobilized complexes show higher activity and better selectivity towards 1-butene formation.

Safety of 3,5-Dimethyl-1H-pyrazole. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Tuskaev, VA; Zubkevich, SV; Saracheno, D; Gagieva, SC; Dorovatovskii, PV; Kononova, EG; Khrustalev, VN; Zarubin, DN; Bulychev, BM; Kissin, YV or concate me.

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Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics

An article Nanoscratch self-healing characteristics of polyvinyl polymer thin films embedded with Al2O3 nanoparticles with thermal and UV energy reactivity WOS:000601000000001 published article about BLOCKED ISOCYANATE; PHOTODIMERIZATION; POLYCARBONATE; MONOMERS; ADHESION; ACID in [Jang, Dong-Hoon; Park, Byung-Min; Han, Kwan-Young] Dankook Univ, Dept Display Engn, Cheonan Si 330714, Chungcheongnam, South Korea; [Kwon, Kyung Ho; Ree, Moonhor] Pohang Univ Sci & Technol, Polymer Res Inst, Div Adv Mat Sci, Dept Chem, Pohang 37673, South Korea in 2020.0, Cited 35.0. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6. Recommanded Product: 3,5-Dimethyl-1H-pyrazole

Self-healing materials can partially or completely heal the damage done to them, and it is expected that their original function will be thereby restored. Herein, we report a novel self-healing polyvinyl (Sh-PV) containing functional polymer that reacts to thermal and ultraviolet (UV) energy. The structure of Sh-PV was characterized by fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance spectroscopy (H-1 NMR). In addition, aluminum oxide (Al2O3) inorganic nanoparticles (NPs) were added and hybridized to improve their poor self-healing efficiency and surface hardness of the coated thin film. Mechanical nanoscratch testing and scanning probe microscopy (SPM) imaging of surface using a nanoindenter were performed to investigate the healing ability of self-healing thin films. The organic-inorganic hybrid self-healing polymer thin film exhibited a 10 % improvement in surface hardness as well as 100 % healing against nanoscale damage compared to virgin self-healing polymers. Here, we discuss and evaluate the optimized method and mechanism of the self-healing system based on the results of self-healing materials and physical recovery methods for healing surface damage.

Recommanded Product: 3,5-Dimethyl-1H-pyrazole. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Jang, DH; Park, BM; Kwon, KH; Ree, M; Han, KY or concate me.

Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics

HPLC of Formula: C5H8N2. Authors Yousef, S; Eimontas, J; Striugas, N; Abdelnaby, MA in PERGAMON-ELSEVIER SCIENCE LTD published article about in [Yousef, Samy] Kaunas Univ Technol, Fac Mech Engn & Design, Dept Prod Engn, LT-51424 Kaunas, Lithuania; [Eimontas, Justas; Striugas, Nerijus] Lithuanian Energy Inst, Lab Combust Proc, Breslaujos 3, LT-44403 Kaunas, Lithuania; [Yousef, Samy] South Ural State Univ, Dept Mat Sci, Lenin Prospect 76, Chelyabinsk 454080, Russia; [Abdelnaby, Mohammed Ali] Akhbar Elyom Acad 6th October, Dept Prod Engn & Printing Technol, Giza, Egypt in 2021.0, Cited 73.0. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6

Mango waste is one of the most promising sources of renewable energy, especially as this waste represents 40% of the weight of mango fruit and contains a large amount of fat and cellulose that can contribute to converting it into energy products using pyrolysis and gasification process. Within this context, this research aims to investigate pyrolysis and gasification kinetic behavior of mango seed shells (MSS) using TG-FTIR-GCeMS system. The experiments were started by analyzing the composition of different types of Egyptian MSS, then their pyrolysis characteristics and chemical decomposition in N-2 and CO2 atmospheres using TG-FTIR system upto 900 degrees C at heating rates in the range 5-30 degrees C/min were studied. The GC/MS system was employed to determine the formulated volatile products at the maximum decomposition temperatures (343-346 degrees C for N-2 and 334-340 degrees C for CO2). Afterwards, the model-free/model-fitting methods, including KissingereAkahiraeSunose, FlynneWalleOzawa, and Friedman, and Distributed Activation Energy Model (DAEM) were used to estimate the kinetic parameters of pyrolysis of MSS in both atmospheres. Finally, chars derived from pyrolysis were exposed to CO2 gasification process, followed by studying of their kinetic behavior in the modified random pore model (MRPM). The results showed that the decomposed MSS were saturated with a huge amount of volatile products, particularly Carbon dioxide and Ethylene oxide (99.27% in CO2 and 20.77% in N-2), while Acetic acid, Propanone, Hexasiloxane, Glycidol, Ethanedial, Ethylene oxide, Formic acid, etc. were the main compounds in case of N-2. Meanwhile, the studies of kinetics of pyrolysis showed that the average activation energies were estimated in the range of 231-262 kJ/mol (N-2) and 259-333 kJ/mol (CO2). Based on that, pyrolysis and gasification can be adapted as promising technologies to valorize MSS and utilize them as a new sustainable source for renewable energy. (C) 2021 Elsevier Ltd. All rights reserved.

HPLC of Formula: C5H8N2. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Yousef, S; Eimontas, J; Striugas, N; Abdelnaby, MA or concate me.

Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics

Recently I am researching about DRUG DISCOVERY; CARDIOVASCULAR SAFETY; BIOLOGICAL-ACTIVITIES; LIBRARIES; BIOAVAILABILITY; COMBINATORIAL; PREDICTION, Saw an article supported by the Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior-Brasil (CAPES)Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) [001]; FAP-UNIVALI. Recommanded Product: 3,5-Dimethyl-1H-pyrazole. Published in SPRINGER BIRKHAUSER in NEW YORK ,Authors: Macarini, AF; Sobrinho, TUC; Rizzi, GW; Correa, R. The CAS is 67-51-6. Through research, I have a further understanding and discovery of 3,5-Dimethyl-1H-pyrazole

In the process of research and development of new drugs, in silico analyzes are widely used. They address the pharmacokinetics of the molecules in study and can predict the binding mode and affinity, using a docking software. This approach can optimize the development of new drugs, reducing costs, time, and resources. In this study, a library of 300 pyrazole-chalcone derivatives were designed, the in silico ADMET (absorption, distribution, metabolism, excretion, and toxicity) properties were evaluated, and a structure-based virtual screening was performed using AutoDock Vina. The docking results exhibited that the derivatives binding mode at the COX-2 active site is similar to celecoxib, the reference drug, and presented similar binding energy. Six compounds were synthetized and tested for in vitro inhibition of the COX-1 and COX-2 isoenzymes and the selectivity index (SI) was calculated. The compound 2a11 showed the best activity for COX-2 (IC50COX-2=0.73M) whereas the control, celecoxib, resulted IC50COX-2=0.88M. All the other compounds synthetized presented better potency for COX-2 inhibition than the control. Compound 2a23 exhibited the higher SI, of 280.17 (IC50COX-1=210.13M/ IC50COX-2=0.75M), while celecoxib was 246.88 (IC50COX-1=217.26M/ IC50COX-2=0.88M). These results corroborate with a possible anti-inflammatory activity and COX-2 selectivity of the new compounds synthetized.

Recommanded Product: 3,5-Dimethyl-1H-pyrazole. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Macarini, AF; Sobrinho, TUC; Rizzi, GW; Correa, R or concate me.

Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics

COA of Formula: C5H8N2. Sun, ML; Wang, L; Zhao, LL; Wang, ZM; Li, PH in [Sun, Mingli; Wang, Lei; Zhao, Lulu; Wang, Zhiming] Taizhou Univ, Adv Res Inst, Taizhou 318000, Zhejiang, Peoples R China; [Sun, Mingli; Wang, Lei; Zhao, Lulu; Li, Pinhua] Huaibei Normal Univ, Dept Chem, Huaibei 235000, Anhui, Peoples R China; [Wang, Lei; Wang, Zhiming; Li, Pinhua] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China published Visible-Light Photoredox Catalyzed C-N Coupling of Quinoxaline-2(1H)-ones with Azoles without External Photosensitizer in 2020.0, Cited 104.0. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.

A visible-light photoredox catalyzed C-N coupling of quinoxaline-2(1H)-ones with azoles in the absence of external photosensitizer has been developed. The protocol employs commercially available pyrazoles and triazoles as amination reagents and shows wide substrate scope, providing the corresponding C3-position amination products in good yields and high regioselectivity under ambient conditions. Investigations indicate that the starting materials and products can act as photosensitizers avoiding use of additional photocatalyst in an autocatalytic manner. In addition,(1)O(2)coexists with O(2)(.-)from molecular oxygen (O-3(2)) via an energy transfer (ET) and single electron transfer (SET) process during the reaction.

COA of Formula: C5H8N2. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Sun, ML; Wang, L; Zhao, LL; Wang, ZM; Li, PH or concate me.

Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics

Huang, XL; Cheng, YZ; Zhang, X; You, SL in [Huang, Xu-Lun; Cheng, Yuan-Zheng; Zhang, Xiao; You, Shu-Li] Chinese Acad Sci, Univ Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem,Ctr Excellence Mol Synth, Shanghai 200032, Peoples R China; [Huang, Xu-Lun; You, Shu-Li] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China; [Zhang, Xiao] Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Key Lab Polymer Sci, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, Fuzhou 350007, Peoples R China published Photoredox-Catalyzed Intermolecular Hydroalkylative Dearomatization of Electron-Deficient Indole Derivatives in 2020.0, Cited 119.0. Product Details of 67-51-6. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6.

Dearomatization of indole derivatives offers a straightforward approach to access diverse indolines. To date, the corresponding dearomative transformations involving electron-deficient indoles are limited. Herein, we report a one-electron strategy for dearomatization of electron-deficient indoles via a photoredox-catalyzed hydroalkylation employing commercially available glycine derivatives as the hydrofunctionalization reagents. Followed by DBU-mediated lactamization, structurally appealing lactam-fused indolines are obtained in good to excellent yields with exclusive selectivity.

Product Details of 67-51-6. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Huang, XL; Cheng, YZ; Zhang, X; You, SL or concate me.

Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics

Authors Kakuchi, R; Okura, Y in NATURE PUBLISHING GROUP published article about MULTICOMPONENT POLYMERIZATION; COPOLYMERS; DENDRIMERS; SYNTHESIZE; CHEMISTRY; LIBRARY in [Kakuchi, Ryohei; Okura, Yamato] Gunma Univ, Fac Sci & Technol, Div Mol Sci, 1-5-1 Tenjin, Kiryu, Gunma 3768515, Japan in 2020.0, Cited 42.0. COA of Formula: C5H8N2. The Name is 3,5-Dimethyl-1H-pyrazole. Through research, I have a further understanding and discovery of 67-51-6

In this study, a novel pyrazole-carbodithioate-based chain transfer agent (CTA) featuring an aldehyde group (CTA-CHO) was designed and synthesized for RAFT polymerization. The obtained CTA-CHO was employed for the RAFT polymerization of styrene to afford well-defined polystyrenes bearing an aldehyde at their chain ends with low D values (similar to 1.1). In addition, the reactivity of the aldehyde moiety at the end of the chain was precisely evaluated, while the Passerini three-component reaction was successfully performed on the aldehyde group.

COA of Formula: C5H8N2. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Kakuchi, R; Okura, Y or concate me.

Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics

Name: 3,5-Dimethyl-1H-pyrazole. Recently I am researching about METAL-COMPLEXES; CU(II); DIETHANOLAMINE; LIGANDS; HFACAC; NODES, Saw an article supported by the . Published in INT UNION CRYSTALLOGRAPHY in CHESTER ,Authors: Vynohradov, OS; Pavlenko, VA; Safyanova, IS; Znovjyak, K; Shova, S; Safarmamadov, SM. The CAS is 67-51-6. Through research, I have a further understanding and discovery of 3,5-Dimethyl-1H-pyrazole

The title compound, [Cu-2(C5H7N2)(C4H10NO2)Cl-2(C5H8N2)], is a pyrazolate aminoalcohol complex which contains two dimethylpyrazole molecules in monodentate and bidentate-bridged coordination modes and a monodeprotonated diethanolamine molecule. Both copper atoms are involved in the formation of non-planar five-membered chelate rings. One Cu atom is in a distorted tetrahedral environment formed by the pyridine nitrogen atom of the protonated dimethylpyrazole molecule, the N atom of the deprotonated bridged dimethylpyrazole, the Cl atom and the bridged O atom of the monodeprotonated diethanolamine. The second Cu atom has an intermediate environment between trigonal bipyramidal and square pyramidal, formed by the N atom of the deprotonated bridged dimethylpyrazole, the Cl atom and the N atom of the aminoalcohol, and two O atoms of the deprotonated and protonated OH groups. In the crystal, N-H center dot center dot center dot Cl hydrogen bonds link the molecules into antisymmetric chains running along the a-axis direction. Adjacent chains are connected by O-H center dot center dot center dot O hydrogen bonds involving the hydroxyl group as donor.

Name: 3,5-Dimethyl-1H-pyrazole. About 3,5-Dimethyl-1H-pyrazole, If you have any questions, you can contact Vynohradov, OS; Pavlenko, VA; Safyanova, IS; Znovjyak, K; Shova, S; Safarmamadov, SM or concate me.

Reference:
Pyrazole – Wikipedia,
,Pyrazoles – an overview | ScienceDirect Topics